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NEET CHEMISTRYMedium

Identify the incorrect statement.

A

The transition metals and their compounds are known for their catalytic activity due to their ability to adopt multiple oxidation states and to form complexes.

B

Interstitial compounds are those that are formed when small atoms like H, C or N are trapped inside the crystal lattices of metals.

C

The oxidation states of chromium in CrO42CrO_4^{2-} and Cr2O72Cr_2O_7^{2-} are not the same.

D

Cr2+(d4)Cr^{2+}(d^4) is a stronger reducing agent than Fe2+(d6)Fe^{2+}(d^6) in water.

Step-by-Step Solution

We analyze each statement based on the NCERT text:

  1. Catalytic Activity: Transition metals are known for catalytic activity due to their ability to adopt multiple oxidation states and form complexes . This statement is correct.
  2. Interstitial Compounds: These are formed when small atoms like H, C, or N are trapped inside the crystal lattices of metals . This statement is correct.
  3. Oxidation States: In chromate (CrO42CrO_4^{2-}): x+4(2)=2x=+6x + 4(-2) = -2 \Rightarrow x = +6. In dichromate (Cr2O72Cr_2O_7^{2-}): 2x+7(2)=22x=12x=+62x + 7(-2) = -2 \Rightarrow 2x = 12 \Rightarrow x = +6. The oxidation state of chromium in both ions is the same (+6) . Therefore, the statement claiming they are not the same is incorrect.
  4. Reducing Agent: Cr2+Cr^{2+} is a stronger reducing agent than Fe2+Fe^{2+}. Cr2+Cr^{2+} (d4d^4) changes to Cr3+Cr^{3+} (d3d^3), which has a stable half-filled t2gt_{2g} configuration. The standard electrode potential E(Cr3+/Cr2+)E^{\ominus}(Cr^{3+}/Cr^{2+}) is 0.41 V-0.41 \text{ V}, while E(Fe3+/Fe2+)E^{\ominus}(Fe^{3+}/Fe^{2+}) is +0.77 V+0.77 \text{ V} . This statement is correct.
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