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NEET CHEMISTRYMedium

A first order reaction has a specific reaction rate of 102 s110^{-2} \text{ s}^{-1}. How much time will it take for 20 g20 \text{ g} of the reactant to reduce to 5 g5 \text{ g}?

A

238.6 s

B

138.6 s

C

346.5 s

D

693.0 s

Step-by-Step Solution

For a first-order reaction, the time required is given by the integrated rate equation:

t=2.303klog[R]0[R]t = \frac{2.303}{k} \log \frac{[R]_0}{[R]}

Given data: Rate constant, k=102 s1k = 10^{-2} \text{ s}^{-1} Initial amount, [R]0=20 g[R]_0 = 20 \text{ g} Final amount, [R]=5 g[R] = 5 \text{ g}

Substituting the values into the equation: t=2.303102log(205)t = \frac{2.303}{10^{-2}} \log \left( \frac{20}{5} \right) t=2.303×102×log(4)t = 2.303 \times 10^2 \times \log(4) t=230.3×2log(2)t = 230.3 \times 2 \log(2) t=230.3×2×0.3010t = 230.3 \times 2 \times 0.3010 t=230.3×0.6020138.64 st = 230.3 \times 0.6020 \approx 138.64 \text{ s}

Therefore, the time required is approximately 138.6 s138.6 \text{ s}.

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