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NEET CHEMISTRYMedium

The complex that does not exhibit optical isomerism is: (en = ethylenediamine)

A

[Co(en)2Cl2]+[\text{Co}(\text{en})_2\text{Cl}_2]^+

B

[Co(NH3)3Cl3][\text{Co}(\text{NH}_3)_3\text{Cl}_3]

C

[Co(en)Cl2(NH3)2]+[\text{Co}(\text{en})\text{Cl}_2(\text{NH}_3)_2]^+

D

[Co(en)3]3+[\text{Co}(\text{en})_3]^{3+}

Step-by-Step Solution

Optical isomerism is not shown by complexes that possess a plane of symmetry. The complex [Co(NH3)3Cl3][\text{Co}(\text{NH}_3)_3\text{Cl}_3] is of the type [Ma3b3][Ma_3b_3]. It exhibits geometrical isomerism, existing as facial (fac) and meridional (mer) isomers. Both of these isomers possess a plane of symmetry and are therefore achiral (optically inactive). On the other hand, octahedral complexes containing bidentate ligands like ethylenediamine (en), such as [Co(en)3]3+[\text{Co}(\text{en})_3]^{3+} or the cis-isomer of [Co(en)2Cl2]+[\text{Co}(\text{en})_2\text{Cl}_2]^+, lack a plane of symmetry and thus exhibit optical isomerism.

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