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NEET CHEMISTRYMedium

Among the following, the most characteristic oxidation states for lead and tin are, respectively:

A

+4, +2

B

+2, +4

C

+4, +4

D

+2, +2

Step-by-Step Solution

Group 14 elements exhibit oxidation states of +2 and +4. As we move down the group, the stability of the higher oxidation state (+4) decreases and the stability of the lower oxidation state (+2) increases due to the inert pair effect (reluctance of s-electrons to participate in bonding).

  1. Lead (Pb): Being at the bottom of the group, the inert pair effect is most pronounced. Consequently, the +2 oxidation state is more stable than the +4 state. This is supported by the fact that Pb4+Pb^{4+} is a strong oxidising agent (Eo=+1.67VE^o = +1.67 V for Pb4+Pb2+Pb^{4+} \rightarrow Pb^{2+}), indicating it readily reduces to the stable Pb2+Pb^{2+} form .
  2. Tin (Sn): Tin lies above Lead. While it shows both +2 and +4 states, the +4 state is more characteristic and stable. Tin(II) acts as a reducing agent (Sn2+Sn^{2+} oxidises to Sn4+Sn^{4+}), whereas Lead(II) is stable.

Therefore, the characteristic oxidation states are +2 for Lead and +4 for Tin.

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