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NEET CHEMISTRYMedium

Concentrated aqueous sulphuric acid is 98% H2SO498\% \text{ H}_2\text{SO}_4 by mass and has a density of 1.80 g mL11.80 \text{ g mL}^{-1}. The volume of acid required to make one litre of 0.1 M0.1 \text{ M} H2SO4\text{H}_2\text{SO}_4 solution is:

A

11.10 mL11.10 \text{ mL}

B

16.65 mL16.65 \text{ mL}

C

22.20 mL22.20 \text{ mL}

D

5.55 mL5.55 \text{ mL}

Step-by-Step Solution

First, we need to find the molarity of the concentrated H2SO4\text{H}_2\text{SO}_4 solution. Consider 1 L1 \text{ L} (1000 mL1000 \text{ mL}) of this solution. Using the given density (1.80 g mL11.80 \text{ g mL}^{-1}), the mass of 1 L1 \text{ L} of solution is: Mass=Volume×Density=1000 mL×1.80 g mL1=1800 g\text{Mass} = \text{Volume} \times \text{Density} = 1000 \text{ mL} \times 1.80 \text{ g mL}^{-1} = 1800 \text{ g} . Since the solution is 98% H2SO498\% \text{ H}_2\text{SO}_4 by mass, the mass of H2SO4\text{H}_2\text{SO}_4 in 1 L1 \text{ L} of solution is: Mass of H2SO4=98100×1800 g=1764 g\text{Mass of H}_2\text{SO}_4 = \frac{98}{100} \times 1800 \text{ g} = 1764 \text{ g} . The molar mass of H2SO4\text{H}_2\text{SO}_4 is 2(1)+32+4(16)=98 g mol12(1) + 32 + 4(16) = 98 \text{ g mol}^{-1} . Number of moles of H2SO4\text{H}_2\text{SO}_4 in 1 L1 \text{ L} of solution =1764 g98 g mol1=18 mol= \frac{1764 \text{ g}}{98 \text{ g mol}^{-1}} = 18 \text{ mol}. Therefore, the molarity (M1M_1) of the concentrated acid is 18 M18 \text{ M} .

To find the volume (V1V_1) of this acid required to make 1 L1 \text{ L} (1000 mL1000 \text{ mL}) of 0.1 M0.1 \text{ M} (M2M_2) solution, we use the dilution formula: M1V1=M2V2M_1V_1 = M_2V_2 18 M×V1=0.1 M×1000 mL18 \text{ M} \times V_1 = 0.1 \text{ M} \times 1000 \text{ mL} V1=10018 mL=5.55 mLV_1 = \frac{100}{18} \text{ mL} = 5.55 \text{ mL}.

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