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NEET CHEMISTRYMedium

Which one of the following ions has electronic configuration [Ar]3d⁶? (At. no: Mn = 25, Fe = 26, Co = 27, Ni = 28)

A

Ni³⁺

B

Mn³⁺

C

Fe³⁺

D

Co³⁺

Step-by-Step Solution

The electronic configuration of an ion is determined by removing electrons from the outermost shell (4s) first, followed by the penultimate shell (3d).

  1. Cobalt (Co, Z=27): The neutral atom configuration is [Ar]3d74s2[Ar] 3d^7 4s^2 .
  2. Formation of Co³⁺: To form the +3 ion, 3 electrons are removed: 2 from the 4s orbital and 1 from the 3d orbital.
  • Co3+Co^{3+} configuration: [Ar]3d6[Ar] 3d^6.

Verification of other options:

  • Ni³⁺ (Z=28): Neutral is [Ar]3d84s2[Ar] 3d^8 4s^2. Removing 3 electrons gives [Ar]3d7[Ar] 3d^7.
  • Mn³⁺ (Z=25): Neutral is [Ar]3d54s2[Ar] 3d^5 4s^2. Removing 3 electrons gives [Ar]3d4[Ar] 3d^4.
  • Fe³⁺ (Z=26): Neutral is [Ar]3d64s2[Ar] 3d^6 4s^2. Removing 3 electrons gives [Ar]3d5[Ar] 3d^5 (half-filled, stable) .
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