The electronic configuration of an ion is determined by removing electrons from the outermost shell (4s) first, followed by the penultimate shell (3d).
- Cobalt (Co, Z=27): The neutral atom configuration is [Ar]3d74s2 .
- Formation of Co³⁺: To form the +3 ion, 3 electrons are removed: 2 from the 4s orbital and 1 from the 3d orbital.
- Co3+ configuration: [Ar]3d6.
Verification of other options:
- Ni³⁺ (Z=28): Neutral is [Ar]3d84s2. Removing 3 electrons gives [Ar]3d7.
- Mn³⁺ (Z=25): Neutral is [Ar]3d54s2. Removing 3 electrons gives [Ar]3d4.
- Fe³⁺ (Z=26): Neutral is [Ar]3d64s2. Removing 3 electrons gives [Ar]3d5 (half-filled, stable) .