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NEET CHEMISTRYMedium

C6H5CH2Br2. H3O+1. Mg, EtherX\text{C}_6\text{H}_5\text{CH}_2\text{Br} \xrightarrow[2.\text{ H}_3\text{O}^+]{1.\text{ Mg, Ether}} \text{X}

The product 'X' in the above reaction is:

A

C6H5CH2OH\text{C}_6\text{H}_5\text{CH}_2\text{OH}

B

C6H5CH3\text{C}_6\text{H}_5\text{CH}_3

C

C6H5CH2CH2C6H5\text{C}_6\text{H}_5\text{CH}_2\text{CH}_2\text{C}_6\text{H}_5

D

C6H5CH2OCH2C6H5\text{C}_6\text{H}_5\text{CH}_2\text{OCH}_2\text{C}_6\text{H}_5

Step-by-Step Solution

The reaction proceeds in two steps:

  1. Formation of Grignard Reagent: Benzyl bromide (C6H5CH2Br\text{C}_6\text{H}_5\text{CH}_2\text{Br}) reacts with magnesium (Mg\text{Mg}) in the presence of dry ether to form benzylmagnesium bromide (C6H5CH2MgBr\text{C}_6\text{H}_5\text{CH}_2\text{MgBr}), which is a Grignard reagent . C6H5CH2Br+Mgdry etherC6H5CH2MgBr\text{C}_6\text{H}_5\text{CH}_2\text{Br} + \text{Mg} \xrightarrow{\text{dry ether}} \text{C}_6\text{H}_5\text{CH}_2\text{MgBr}
  2. Hydrolysis: Grignard reagents are highly reactive and react with any source of a proton (like water, alcohols, or acids) to form corresponding hydrocarbons. Here, the addition of H3O+\text{H}_3\text{O}^+ (acidic hydrolysis) provides protons that react with the Grignard reagent to form toluene (C6H5CH3\text{C}_6\text{H}_5\text{CH}_3). C6H5CH2MgBr+H3O+C6H5CH3+Mg(OH)Br+H+\text{C}_6\text{H}_5\text{CH}_2\text{MgBr} + \text{H}_3\text{O}^+ \rightarrow \text{C}_6\text{H}_5\text{CH}_3 + \text{Mg}(\text{OH})\text{Br} + \text{H}^+

Thus, the final product 'X' is toluene (C6H5CH3\text{C}_6\text{H}_5\text{CH}_3).

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