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NEET CHEMISTRYMedium

The volume of CO2CO_2 obtained by the complete decomposition of 9.85 g9.85\text{ g} of BaCO3BaCO_3 is:

A

2.24 L

B

1.12 L

C

0.84 L

D

0.56 L

Step-by-Step Solution

  1. Write the balanced chemical equation: BaCO3(s)ΔBaO(s)+CO2(g)BaCO_3(s) \xrightarrow{\Delta} BaO(s) + CO_2(g)
  2. Calculate the Molar Mass of BaCO3BaCO_3: Atomic masses: Ba=137Ba = 137, C=12C = 12, O=16O = 16. M=137+12+(3×16)=137+12+48=197 g/molM = 137 + 12 + (3 \times 16) = 137 + 12 + 48 = 197\text{ g/mol}
  3. Calculate moles of BaCO3BaCO_3: n=Given MassMolar Mass=9.85 g197 g/mol=0.05 moln = \frac{\text{Given Mass}}{\text{Molar Mass}} = \frac{9.85\text{ g}}{197\text{ g/mol}} = 0.05\text{ mol}
  4. Apply Stoichiometry: From the equation, 1 mol1\text{ mol} of BaCO3BaCO_3 produces 1 mol1\text{ mol} of CO2CO_2. Therefore, 0.05 mol0.05\text{ mol} of BaCO3BaCO_3 will produce 0.05 mol0.05\text{ mol} of CO2CO_2.
  5. Calculate Volume at STP: At STP, 1 mol1\text{ mol} of any ideal gas occupies 22.4 L22.4\text{ L}. V=n×22.4 L=0.05×22.4=1.12 LV = n \times 22.4\text{ L} = 0.05 \times 22.4 = 1.12\text{ L}
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