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NEET CHEMISTRYMedium

For an endothermic reaction, energy of activation is EaE_a and enthalpy of reaction is ΔH\Delta H (both of these in kJ/mol). Minimum value of EaE_a will be:

A

Less than ΔH\Delta H

B

Equal to ΔH\Delta H

C

More than ΔH\Delta H

D

Equal to zero

Step-by-Step Solution

For any chemical reaction, the enthalpy of reaction (ΔH\Delta H) is the difference between the activation energy of the forward reaction (EaE_a) and the activation energy of the backward reaction (Ea(backward)E_{a(\text{backward})}):

ΔH=EaEa(backward)\Delta H = E_a - E_{a(\text{backward})}

For an endothermic reaction, the energy of the products is greater than the energy of the reactants, meaning ΔH\Delta H is positive (>0> 0). Therefore, Ea>Ea(backward)E_a > E_{a(\text{backward})}.

Since the activation energy of the backward reaction must be a positive value (Ea(backward)>0E_{a(\text{backward})} > 0), we can write:

Ea=ΔH+Ea(backward)E_a = \Delta H + E_{a(\text{backward})}

Thus, the activation energy (EaE_a) must always be strictly greater than the enthalpy of the reaction (ΔH\Delta H).

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