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NEET CHEMISTRYEasy

Which of the following oxidation states are the most characteristics for lead and tin respectively?

A

+4,+2+4, +2

B

+2,+4+2, +4

C

+4,+4+4, +4

D

+2,+2+2, +2

Step-by-Step Solution

Due to the inert pair effect, the reluctance of the valence ns2ns^2 electrons to participate in bonding increases down the group. In the carbon family (Group 14), the stability of the lower oxidation state (+2+2) increases as we move from lighter to heavier elements, while the stability of the higher oxidation state (+4+4) decreases. Consequently, the most characteristic and stable oxidation state for lead (Pb\text{Pb}) is +2+2, whereas for tin (Sn\text{Sn}) the +4+4 oxidation state is more stable. Therefore, for lead and tin respectively, the characteristic oxidation states are +2+2 and +4+4.

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