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NEET CHEMISTRYEasy

Given below are two statements: Statement I: Benzoic acid produces effervescence on treatment with aq. NaHCO3NaHCO_3. Statement II: The effervescence is due to the release of hydrogen gas. In the light of the above statements, choose the most appropriate answer from the options give below:

A

Both Statement I and Statement II are correct.

B

Both Statement I and Statement II are incorrect.

C

Statement I is correct but Statement II is incorrect.

D

Statement I is incorrect but Statement II is correct.

Step-by-Step Solution

Carboxylic acids (like Benzoic acid) are stronger acids than carbonic acid (H2CO3H_2CO_3). Consequently, they decompose carbonates and bicarbonates to evolve carbon dioxide gas (CO2CO_2), which produces brisk effervescence. The reaction is represented as: C6H5COOH+NaHCO3C6H5COONa+H2O+CO2C_6H_5COOH + NaHCO_3 \rightarrow C_6H_5COONa + H_2O + CO_2 \uparrow. Therefore, Statement I is correct because the reaction occurs, but Statement II is incorrect because the gas released is CO2CO_2, not hydrogen (H2H_2).

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