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NEET CHEMISTRYMedium

The order of energy absorbed, which is responsible for the color of complexes, is: (A) [Ni(H2O)2(en)2]2+[Ni(H_2O)_2(en)_2]^{2+} (B) [Ni(H2O)4(en)]2+[Ni(H_2O)_4(en)]^{2+} (C) [Ni(en)3]2+[Ni(en)_3]^{2+}

A

B > A > C

B

A > B > C

C

C > B > A

D

C > A > B

Step-by-Step Solution

The energy of light absorbed by a coordination complex is directly proportional to its crystal field splitting energy (Δo\Delta_o), which in turn depends on the field strength of the ligands present. According to the spectrochemical series, ethylenediamine (enen) is a stronger field ligand than water (H2OH_2O). As the number of enen ligands replacing H2OH_2O increases, the magnitude of Δo\Delta_o increases, leading to the absorption of light of higher energy (shorter wavelength). The number of enen ligands in the given complexes is: (C) [Ni(en)3]2+[Ni(en)_3]^{2+} : 3 enen ligands (Maximum Δo\Delta_o) (A) [Ni(H2O)2(en)2]2+[Ni(H_2O)_2(en)_2]^{2+} : 2 enen ligands (B) [Ni(H2O)4(en)]2+[Ni(H_2O)_4(en)]^{2+} : 1 enen ligand (Minimum Δo\Delta_o) Therefore, the correct order of energy absorbed is C > A > B.

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