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NEET CHEMISTRYEasy

Which one of the following statements is true about the structure of CO32CO_3^{2-} ion?

A

It can be explained by considering sp3sp^3 hybridisation.

B

Out of the three COC–O bonds, two are longer and one is shorter.

C

It has three sigma and three π\pi-bonds.

D

All three COC–O bonds are equal in length with a bond order in between 1 and 2.

Step-by-Step Solution

According to the sources, a single Lewis structure for the carbonate ion (CO32CO_3^{2-}), showing one double bond and two single bonds, is inadequate because experimental data proves that all three carbon-to-oxygen bonds are equivalent . This equivalence is explained by resonance, where the ion is a hybrid of three canonical forms . Consequently, all three bonds have the same length, which is intermediate between a single and a double bond, resulting in a bond order between 1 and 2 (specifically 1.33) . Furthermore, the central carbon atom in the carbonate ion is sp2sp^2 hybridised to maintain its trigonal planar geometry, not sp3sp^3 . The structure contains three sigma (σ\sigma ) bonds and one delocalised \pi (π\pi ) bond, rather than three separate π\pi -bonds .

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