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NEET CHEMISTRYMedium

An incorrect statement among the following is :

A

La(OH)3La(OH)_3 is less basic than Lu(OH)3Lu(OH)_3

B

In Lanthanide series, ionic radius of Ln3+Ln^{3+} ions decreases.

C

La is an element of a transition and not of Lanthanide series.

D

The atomic radius of Zr and Hf are the same because of Lanthanide contraction.

Step-by-Step Solution

Due to lanthanoid contraction, the size of Ln3+Ln^{3+} ions decreases regularly from La3+La^{3+} to Lu3+Lu^{3+}. As the size of the cation decreases, the covalent character of the LnOHLn-OH bond increases (according to Fajan's rules). Consequently, the basic strength of the hydroxides steadily decreases from La(OH)3La(OH)_3 to Lu(OH)3Lu(OH)_3. Thus, La(OH)3La(OH)_3 is the most basic and Lu(OH)3Lu(OH)_3 is the least basic. Therefore, the statement 'La(OH)3La(OH)_3 is less basic than Lu(OH)3Lu(OH)_3' is incorrect. The other statements are correct: the ionic radius of Ln3+Ln^{3+} ions decreases along the series , La (Z=57Z=57) is considered a d-block transition element , and the atomic radii of Zr (160 pm) and Hf (159 pm) are almost identical due to lanthanoid contraction .

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