For a given exothermic reaction, and are the equilibrium constants at temperatures and respectively. Assuming that heat of reaction is constant in a temperature range between and , it is readily observed that (assuming ):
According to the van't Hoff equation: For an exothermic reaction, is negative (). Assuming , the term is positive. Therefore, the right side of the equation becomes negative, meaning . This implies , or .
Alternatively, according to Le Chatelier's principle, an increase in temperature for an exothermic reaction shifts the equilibrium in the backward direction to counteract the added heat. This leads to a decrease in the value of the equilibrium constant. Hence, the equilibrium constant at the higher temperature will be less than at the lower temperature .
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