Back to Directory
NEET CHEMISTRYMedium

For a given exothermic reaction, KpK_p and KpK'_p are the equilibrium constants at temperatures T1T_1 and T2T_2 respectively. Assuming that heat of reaction is constant in a temperature range between T1T_1 and T2T_2, it is readily observed that (assuming T2>T1T_2 > T_1):

A

Kp>KpK_p > K'_p

B

Kp<KpK_p < K'_p

C

Kp=KpK_p = K'_p

D

Kp=1/KpK_p = 1/K'_p

Step-by-Step Solution

According to the van't Hoff equation: logKpKp=ΔH2.303R(1T11T2)\log \frac{K'_p}{K_p} = \frac{\Delta H}{2.303 R} \left( \frac{1}{T_1} - \frac{1}{T_2} \right) For an exothermic reaction, ΔH\Delta H is negative (ΔH<0\Delta H < 0). Assuming T2>T1T_2 > T_1, the term (1T11T2)\left( \frac{1}{T_1} - \frac{1}{T_2} \right) is positive. Therefore, the right side of the equation becomes negative, meaning logKpKp<0\log \frac{K'_p}{K_p} < 0. This implies KpKp<1\frac{K'_p}{K_p} < 1, or Kp>KpK_p > K'_p.

Alternatively, according to Le Chatelier's principle, an increase in temperature for an exothermic reaction shifts the equilibrium in the backward direction to counteract the added heat. This leads to a decrease in the value of the equilibrium constant. Hence, the equilibrium constant KpK'_p at the higher temperature T2T_2 will be less than KpK_p at the lower temperature T1T_1.

Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started
Solved: CHEMISTRY Question for NEET | Sushrut