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NEET CHEMISTRYEasy

If the half-life is independent of its initial concentration, then the order of the reaction is:

A

0

B

1

C

3

D

2

Step-by-Step Solution

For a first-order reaction, the half-life period (t1/2t_{1/2}) is given by the expression t1/2=0.693kt_{1/2} = \frac{0.693}{k}. This equation clearly shows that the half-life of a first-order reaction is constant and independent of the initial concentration of the reacting species. In general, for an nthn^{\text{th}} order reaction, the half-life is inversely proportional to the initial concentration raised to the power of (n1)(n-1), i.e., t1/21[R]0n1t_{1/2} \propto \frac{1}{[R]_0^{n-1}}. For n=1n=1, t1/2[R]00t_{1/2} \propto [R]_0^0, meaning it is independent of the initial concentration.

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