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NEET Hard

The compound C7H8C_7H_8 undergoes the following reactions: C7H83Cl2/ΔABr2/FeBZn/HClCC_7H_8 \xrightarrow{3Cl_2/\Delta} A \xrightarrow{Br_2/Fe} B \xrightarrow{Zn/HCl} C. The product 'C' is

1

3-bromo-2,4,6-trichlorotoluene

2

o-bromotoluene

3

m-bromotoluene

4

p-bromotoluene

Step-by-Step Solution

Toluene (C7H8C_7H_8) reacts with 3Cl2/Δ3Cl_2/\Delta to form benzotrichloride. Then Br2/FeBr_2/Fe performs electrophilic substitution at the meta position due to the deactivating CCl3-CCl_3 group. Finally, Zn/HClZn/HCl reduces CCl3-CCl_3 to CH3-CH_3.

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