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The molecules of a given mass of gas have RMS velocity of 200 ms1200 \text{ ms}^{-1} at 27C27^\circ\text{C} and 1.0×105 Nm21.0 \times 10^5 \text{ Nm}^{-2} pressure. When the temperature and the pressure of the gas are respectively, 127C127^\circ\text{C} and 0.05×105 Nm20.05 \times 10^5 \text{ Nm}^{-2}, the RMS velocity of its molecules in ms1\text{ms}^{-1} is:

A

4003\frac{400}{\sqrt{3}}

B

10023\frac{100\sqrt{2}}{3}

C

1003\frac{100}{3}

D

1002100\sqrt{2}

Step-by-Step Solution

  1. Identify the Formula: The Root Mean Square (RMS) velocity of gas molecules is given by vrms=3RTMv_{rms} = \sqrt{\frac{3RT}{M}}, where RR is the gas constant, TT is the absolute temperature, and MM is the molar mass.
  2. Analyze Dependencies: For a given mass of gas (constant MM), the RMS velocity depends only on temperature (vrmsTv_{rms} \propto \sqrt{T}). It is independent of pressure changes if the gas remains ideal.
  3. Convert Units: Initial Temperature (T1T_1) = 27C=27+273=300 K27^\circ\text{C} = 27 + 273 = 300 \text{ K}. Final Temperature (T2T_2) = 127C=127+273=400 K127^\circ\text{C} = 127 + 273 = 400 \text{ K}.
  4. Calculate New Velocity: v2v1=T2T1\frac{v_2}{v_1} = \sqrt{\frac{T_2}{T_1}} v2200=400300=43=23\frac{v_2}{200} = \sqrt{\frac{400}{300}} = \sqrt{\frac{4}{3}} = \frac{2}{\sqrt{3}}
  • v2=200×23=4003 ms1v_2 = 200 \times \frac{2}{\sqrt{3}} = \frac{400}{\sqrt{3}} \text{ ms}^{-1}.
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