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The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å. The wavelength of the second spectral line in the Balmer series of singly ionized helium atom is:

A

1215 Å

B

1640 Å

C

2430 Å

D

4687 Å

Step-by-Step Solution

The wavelength (λ\lambda) of a spectral line is given by the Rydberg formula: 1λ=RZ2(1n121n22)\frac{1}{\lambda} = R Z^2 \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right).

  1. Hydrogen atom (Z=1): The first line of the Balmer series corresponds to the transition from n2=3n_2=3 to n1=2n_1=2. 1λH=R(1)2(122132)=R(1419)=5R36\frac{1}{\lambda_H} = R(1)^2 \left(\frac{1}{2^2} - \frac{1}{3^2}\right) = R\left(\frac{1}{4} - \frac{1}{9}\right) = \frac{5R}{36}. Given λH=6561A˚\lambda_H = 6561 \mathring{A}.

  2. Singly ionized Helium atom (He+^+, Z=2): The second line of the Balmer series corresponds to the transition from n2=4n_2=4 to n1=2n_1=2. 1λHe=R(2)2(122142)=4R(14116)=4R(316)=3R4\frac{1}{\lambda_{He}} = R(2)^2 \left(\frac{1}{2^2} - \frac{1}{4^2}\right) = 4R\left(\frac{1}{4} - \frac{1}{16}\right) = 4R\left(\frac{3}{16}\right) = \frac{3R}{4}.

  3. Ratio: λHeλH=5R/363R/4=536×43=527\frac{\lambda_{He}}{\lambda_H} = \frac{5R/36}{3R/4} = \frac{5}{36} \times \frac{4}{3} = \frac{5}{27}. λHe=6561×527=243×5=1215A˚\lambda_{He} = 6561 \times \frac{5}{27} = 243 \times 5 = 1215 \mathring{A}.

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