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NEET PHYSICSMedium

A certain number of spherical drops of a liquid of radius rr coalesce to form a single drop of radius RR and volume VV. If TT is the surface tension of the liquid, then:

A

Energy =4VT(1r1R)= 4VT\left(\frac{1}{r}-\frac{1}{R}\right) is released

B

Energy =3VT(1r+1R)= 3VT\left(\frac{1}{r}+\frac{1}{R}\right) is released

C

Energy =3VT(1r1R)= 3VT\left(\frac{1}{r}-\frac{1}{R}\right) is released

D

Energy is neither released nor absorbed

Step-by-Step Solution

  1. Principle: When smaller drops coalesce to form a larger drop, the total volume remains conserved, but the total surface area decreases. The decrease in surface energy appears as released energy .
  2. Formulas:
  • Volume of a sphere: V=43πR3=n43πr3V = \frac{4}{3}\pi R^3 = n \cdot \frac{4}{3}\pi r^3 (where nn is the number of small drops).
  • Surface Area: A=4πR2A = 4\pi R^2.
  • Surface Energy: E=T×AE = T \times A.
  1. Derivation:
  • Initial Surface Area (AiA_i): n(4πr2)n(4\pi r^2). Using V=n43πr3V = n\frac{4}{3}\pi r^3, we can substitute n=3V4πr3n = \frac{3V}{4\pi r^3}. Thus, Ai=(3V4πr3)4πr2=3VrA_i = \left(\frac{3V}{4\pi r^3}\right)4\pi r^2 = \frac{3V}{r}.
  • Final Surface Area (AfA_f): 4πR24\pi R^2. Using V=43πR3V = \frac{4}{3}\pi R^3, we get Af=3VRA_f = \frac{3V}{R}.
  • Change in Energy (ΔE\Delta E): T(AiAf)=T(3Vr3VR)=3VT(1r1R)T(A_i - A_f) = T\left(\frac{3V}{r} - \frac{3V}{R}\right) = 3VT\left(\frac{1}{r} - \frac{1}{R}\right).
  1. Conclusion: Since r<Rr < R, the term (1r1R)(\frac{1}{r} - \frac{1}{R}) is positive, indicating energy is released due to the decrease in surface area.
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