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One mole of an ideal diatomic gas undergoes a transition from AA to BB along a path ABAB as shown in the figure. The change in internal energy of the gas during the transition is

A

20 kJ20\text{ kJ}

B

20 kJ-20\text{ kJ}

C

20 J20\text{ J}

D

12 kJ-12\text{ kJ}

Step-by-Step Solution

For an ideal diatomic gas, the molar specific heat at constant volume is Cv=52RC_v = \frac{5}{2}R. The change in internal energy is a state function and depends only on the initial and final temperatures. It can be expressed as: ΔU=nCvΔT=n(52R)(TBTA)=52(nRTBnRTA)\Delta U = nC_v\Delta T = n\left(\frac{5}{2}R\right)(T_B - T_A) = \frac{5}{2}(nR T_B - nR T_A) Using the ideal gas equation PV=nRTPV = nRT, this becomes: ΔU=52(PBVBPAVA)\Delta U = \frac{5}{2}(P_B V_B - P_A V_A) From the standard PP-VV indicator diagram given in this PYQ, the coordinates for the initial state AA and final state BB are A(4 m3,5 kPa)A \equiv (4\text{ m}^3, 5\text{ kPa}) and B(6 m3,2 kPa)B \equiv (6\text{ m}^3, 2\text{ kPa}). Therefore, PAVA=5 kPa×4 m3=20 kJP_A V_A = 5\text{ kPa} \times 4\text{ m}^3 = 20\text{ kJ} and PBVB=2 kPa×6 m3=12 kJP_B V_B = 2\text{ kPa} \times 6\text{ m}^3 = 12\text{ kJ}. Substituting these values into the internal energy equation: ΔU=52(12 kJ20 kJ)=52(8 kJ)=20 kJ\Delta U = \frac{5}{2}(12\text{ kJ} - 20\text{ kJ}) = \frac{5}{2}(-8\text{ kJ}) = -20\text{ kJ}.

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