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NEET PHYSICSMedium

Figure below shows two paths that may be taken by a gas to go from a state AA to a state CC. In process ABAB, 400 J400\text{ J} of heat is added to the system and in process BCBC, 100 J100\text{ J} of heat is added to the system. The heat absorbed by the system in the process ACAC will be:

A

380 J380\text{ J}

B

500 J500\text{ J}

C

460 J460\text{ J}

D

300 J300\text{ J}

Step-by-Step Solution

According to the first law of thermodynamics, ΔU=QW\Delta U = Q - W. For the path ABCABC, the total heat added is QABC=QAB+QBC=400 J+100 J=500 JQ_{ABC} = Q_{AB} + Q_{BC} = 400\text{ J} + 100\text{ J} = 500\text{ J}. From the standard PP-VV diagram given in this PYQ, the coordinates are: A(2×103 m3,2×104 Pa)A \equiv (2 \times 10^{-3}\text{ m}^3, 2 \times 10^4\text{ Pa}) B(2×103 m3,6×104 Pa)B \equiv (2 \times 10^{-3}\text{ m}^3, 6 \times 10^4\text{ Pa}) C(4×103 m3,6×104 Pa)C \equiv (4 \times 10^{-3}\text{ m}^3, 6 \times 10^4\text{ Pa}) Work done in path ABAB (isochoric process, ΔV=0\Delta V = 0) is WAB=0W_{AB} = 0. Work done in path BCBC (isobaric process) is WBC=PB(VCVB)=6×104×(42)×103=120 JW_{BC} = P_B(V_C - V_B) = 6 \times 10^4 \times (4 - 2) \times 10^{-3} = 120\text{ J}. Total work done along path ABCABC is WABC=WAB+WBC=120 JW_{ABC} = W_{AB} + W_{BC} = 120\text{ J}. Change in internal energy is ΔU=QABCWABC=500 J120 J=380 J\Delta U = Q_{ABC} - W_{ABC} = 500\text{ J} - 120\text{ J} = 380\text{ J}. Since internal energy is a state function, ΔU\Delta U for path ACAC is also 380 J380\text{ J}. Work done along path ACAC is the area of the trapezium under the curve ACAC: WAC=12(PA+PC)(VCVA)=12(2×104+6×104)(42)×103=12(8×104)(2×103)=80 JW_{AC} = \frac{1}{2} (P_A + P_C)(V_C - V_A) = \frac{1}{2}(2 \times 10^4 + 6 \times 10^4)(4 - 2) \times 10^{-3} = \frac{1}{2}(8 \times 10^4)(2 \times 10^{-3}) = 80\text{ J}. Therefore, heat absorbed in path ACAC is QAC=ΔU+WAC=380 J+80 J=460 JQ_{AC} = \Delta U + W_{AC} = 380\text{ J} + 80\text{ J} = 460\text{ J}.

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