According to the first law of thermodynamics, ΔU=Q−W.
For the path ABC, the total heat added is QABC=QAB+QBC=400 J+100 J=500 J.
From the standard P-V diagram given in this PYQ, the coordinates are:
A≡(2×10−3 m3,2×104 Pa)
B≡(2×10−3 m3,6×104 Pa)
C≡(4×10−3 m3,6×104 Pa)
Work done in path AB (isochoric process, ΔV=0) is WAB=0.
Work done in path BC (isobaric process) is WBC=PB(VC−VB)=6×104×(4−2)×10−3=120 J.
Total work done along path ABC is WABC=WAB+WBC=120 J.
Change in internal energy is ΔU=QABC−WABC=500 J−120 J=380 J.
Since internal energy is a state function, ΔU for path AC is also 380 J.
Work done along path AC is the area of the trapezium under the curve AC:
WAC=21(PA+PC)(VC−VA)=21(2×104+6×104)(4−2)×10−3=21(8×104)(2×10−3)=80 J.
Therefore, heat absorbed in path AC is QAC=ΔU+WAC=380 J+80 J=460 J.