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In a mass spectrometer used for measuring the masses of ions, the ions are initially accelerated by an electric potential VV and then made to describe semi-circular paths of radius RR using a magnetic field BB. If VV and BB are kept constant, the ratio of (Charge on the ionMass of the ion)\left(\frac{\text{Charge on the ion}}{\text{Mass of the ion}}\right) (qm)\left(\frac{q}{m}\right) will be proportional to:

A

1R\frac{1}{R}

B

1R2\frac{1}{R^2}

C

R2R^2

D

RR

Step-by-Step Solution

  1. Acceleration by Electric Field: When an ion with charge qq and mass mm is accelerated from rest through a potential difference VV, the work done by the electric field equals the gain in kinetic energy. qV=12mv2    v=2qVmqV = \frac{1}{2}mv^2 \implies v = \sqrt{\frac{2qV}{m}}
  2. Motion in Magnetic Field: Upon entering a uniform magnetic field BB perpendicular to its velocity, the Lorentz force provides the necessary centripetal force for circular motion . qvB=mv2R    v=qBRmqvB = \frac{mv^2}{R} \implies v = \frac{qBR}{m}
  3. Relating Specific Charge (q/m) to R: Substitute the expression for velocity (vv) from the magnetic field equation into the energy equation: qV=12m(qBRm)2qV = \frac{1}{2}m \left( \frac{qBR}{m} \right)^2 qV=12mq2B2R2m2qV = \frac{1}{2}m \frac{q^2 B^2 R^2}{m^2} V=12qB2R2mV = \frac{1}{2} \frac{q B^2 R^2}{m} Rearranging to find the charge-to-mass ratio (q/mq/m): qm=2VB2R2\frac{q}{m} = \frac{2V}{B^2 R^2}
  4. Conclusion: Since VV and BB are constant, the specific charge is inversely proportional to the square of the radius . qm1R2\frac{q}{m} \propto \frac{1}{R^2}
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