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The molar specific heats of an ideal gas at constant pressure and volume are denoted by CPC_P and CVC_V, respectively. If γ=CPCV\gamma = \frac{C_P}{C_V} and RR is the universal gas constant, then CVC_V is equal to:

A

Rγ1\frac{R}{\gamma - 1}

B

γ1R\frac{\gamma - 1}{R}

C

γR\gamma R

D

(γ1)Rγ+1\frac{(\gamma - 1)R}{\gamma + 1}

Step-by-Step Solution

For an ideal gas, the relationship between the molar specific heat at constant pressure (CPC_P) and the molar specific heat at constant volume (CVC_V) is given by Mayer's relation : CPCV=RC_P - C_V = R where RR is the universal gas constant.

The adiabatic index (or heat capacity ratio) γ\gamma is defined as: γ=CPCV    CP=γCV\gamma = \frac{C_P}{C_V} \implies C_P = \gamma C_V

Substituting this into Mayer's relation: γCVCV=R\gamma C_V - C_V = R CV(γ1)=RC_V(\gamma - 1) = R CV=Rγ1C_V = \frac{R}{\gamma - 1}

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