Three liquids of densities ρ1,ρ2 and ρ3 (with ρ1>ρ2>ρ3), having the same value of surface tension T, rise to the same height in three identical capillaries. The angles of contact θ1,θ2 and θ3 obey:
A
2π>θ1>θ2>θ3≥0
B
0≤θ1<θ2<θ3<2π
C
2π<θ1<θ2<θ3<π
D
π>θ1>θ2>θ3>2π
Step-by-Step Solution
Capillary Rise Formula: The height h to which a liquid rises in a capillary tube of radius r is given by the formula:
h=rρg2Tcosθ
where T is surface tension, θ is the angle of contact, ρ is the density of the liquid, and g is acceleration due to gravity .
Analyze Dependencies: We are given that h,T,r, and g are the same for all three liquids. Rearranging the formula for the variable terms:
cosθ=2Thrg⋅ρ
Since 2Thrg is a constant (K), we have:
cosθ=Kρ
This implies cosθ∝ρ.
Apply Conditions: We are given densities ρ1>ρ2>ρ3. Therefore:
cosθ1>cosθ2>cosθ3
Behavior of Cosine: For capillary rise (h>0), the angle of contact θ must be acute, i.e., 0≤θ<2π. In this range, the cosine function is a decreasing function (as angle increases, cosine value decreases).
Therefore, the inequality for the angles reverses:
θ1<θ2<θ3
Conclusion: The correct relationship is 0≤θ1<θ2<θ3<2π.
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