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In hydrogen spectrum, the shortest wavelength in the Balmer series is \lambda . The shortest wavelength in the Brackett series is:

A

16\lambda

B

2\lambda

C

4\lambda

D

9\lambda

Step-by-Step Solution

The shortest wavelength (series limit) corresponds to the transition from n2=n_2 = \infty. For the Balmer series, the transition is to n1=2n_1 = 2 . Using the Rydberg formula 1λ=R(1n121n22)\frac{1}{\lambda} = R \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right), we get 1λ=R(1220)=R4\frac{1}{\lambda} = R \left(\frac{1}{2^2} - 0\right) = \frac{R}{4}, so λ=4R\lambda = \frac{4}{R}. For the Brackett series, the transition is to n1=4n_1 = 4 . The shortest wavelength λ\lambda' is given by 1λ=R(1420)=R16\frac{1}{\lambda'} = R \left(\frac{1}{4^2} - 0\right) = \frac{R}{16}, so λ=16R\lambda' = \frac{16}{R}. Comparing the two, λ=4(4R)=4λ\lambda' = 4 \left(\frac{4}{R}\right) = 4\lambda.

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