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Thermodynamic processes are indicated in the following diagram. Match the following:

Column-I (P) Process I (Q) Process II (R) Process III (S) Process IV

Column-II (a) Adiabatic (b) Isobaric (c) Isochoric (d) Isothermal

A

P → c, Q → a, R → d, S → b

B

P → c, Q → d, R → b, S → a

C

P → d, Q → b, R → b, S → c

D

P → a, Q → c, R → d, S → b

Step-by-Step Solution

To match the processes with their corresponding P-V diagram curves, we apply the characteristics of thermodynamic processes for an ideal gas:

  1. Isochoric Process (Constant Volume): The work done is zero, and the volume (VV) remains constant while pressure (PP) changes. On a P-V graph, this corresponds to a vertical line. Thus, Process I matches with (c) Isochoric.

  2. Isobaric Process (Constant Pressure): The pressure (PP) remains constant while volume changes. On a P-V graph, this corresponds to a horizontal line. Thus, Process IV matches with (b) Isobaric.

  3. Isothermal vs. Adiabatic (Expansion): Both processes represent curves with negative slopes. However, the magnitude of the slope for an adiabatic process (dPdV=γPV|\frac{dP}{dV}| = \gamma \frac{P}{V}) is greater than that for an isothermal process (dPdV=PV|\frac{dP}{dV}| = \frac{P}{V}) because the heat capacity ratio γ\gamma (gamma) is greater than 1. Therefore, the adiabatic curve is steeper (falls more rapidly) than the isothermal curve.

  • Process II: Being the steeper curve in standard representations of expansion, it corresponds to (a) Adiabatic.
  • Process III: Being the less steep curve, it corresponds to (d) Isothermal.

Matching: P (Process I) → c (Isochoric) Q (Process II) → a (Adiabatic) R (Process III) → d (Isothermal) S (Process IV) → b (Isobaric)

This sequence corresponds to Option 1 .

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