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1 g of water of volume 1 cm31 \text{ cm}^3 at 100C100^{\circ}\text{C} is converted into steam at the same temperature under normal atmospheric pressure 1×105 Pa\approx 1 \times 10^5 \text{ Pa}. The volume of steam formed equals 1671 cm31671 \text{ cm}^3. If the specific latent heat of vaporization of water is 2256 J/g2256 \text{ J/g}, the change in internal energy is:

A

2423 J

B

2089 J

C

167 J

D

2256 J

Step-by-Step Solution

According to the First Law of Thermodynamics, the change in internal energy (ΔU\Delta U) is given by: ΔQ=ΔU+ΔW    ΔU=ΔQΔW\Delta Q = \Delta U + \Delta W \implies \Delta U = \Delta Q - \Delta W

  1. Calculate Heat Absorbed (ΔQ\Delta Q): The heat absorbed during the phase change is determined by the specific latent heat of vaporization (LL) and the mass (mm). ΔQ=m×L\Delta Q = m \times L ΔQ=1 g×2256 J/g=2256 J\Delta Q = 1 \text{ g} \times 2256 \text{ J/g} = 2256 \text{ J}

  2. Calculate Work Done (ΔW\Delta W): Work done during expansion at constant pressure is given by ΔW=PΔV\Delta W = P\Delta V. Pressure (PP) = 1×105 Pa1 \times 10^5 \text{ Pa} Change in volume (ΔV\Delta V) = VsteamVwater=1671 cm31 cm3=1670 cm3V_{\text{steam}} - V_{\text{water}} = 1671 \text{ cm}^3 - 1 \text{ cm}^3 = 1670 \text{ cm}^3

  • Convert ΔV\Delta V to SI units (textm3\\text{m}^3): 1670×106 m31670 \times 10^{-6} \text{ m}^3

ΔW=(1×105 Pa)×(1670×106 m3)=167 J\Delta W = (1 \times 10^5 \text{ Pa}) \times (1670 \times 10^{-6} \text{ m}^3) = 167 \text{ J}

  1. Calculate Internal Energy Change (ΔU\Delta U): ΔU=2256 J167 J=2089 J\Delta U = 2256 \text{ J} - 167 \text{ J} = 2089 \text{ J}
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