The quantity 21ε0E2 represents the energy density (energy per unit volume) of an electric field.
The dimensional formula of energy is [ML2T−2] and that of volume is [L3].
Therefore, the dimensional formula of energy density is [L3][ML2T−2]=[ML−1T−2].
Alternatively, you can derive it by substituting the individual dimensions:
Dimension of permittivity of free space, ε0=[M−1L−3T4A2]
Dimension of electric field, E=ChargeForce=[AT][MLT−2]=[MLT−3A−1]
Dimension of ε0E2=[M−1L−3T4A2]×[MLT−3A−1]2=[M−1L−3T4A2]×[M2L2T−6A−2]=[ML−1T−2].