Let En = -(me^4)/(8ε_0^2 n^2 h^2) be the energy of the nth level of H-atom. If all the H-atoms are in the ground state and radiation of frequency (E2 - E1)/h falls on it, then: (a) it will not be absorbed at all. (b) some of the atoms will move to the first excited state. (c) all atoms will be excited to the n=2 state. (d) no atoms will make a transition to the n=3 state.
Choose the correct option:
(b), (d)
(a), (d)
(b), (c), (d)
(c), (d)
According to Bohr's frequency rule (Source , Eq 2.10), the frequency of radiation absorbed or emitted during a transition is given by . Here, the incident radiation has frequency , which corresponds exactly to the energy gap between the ground state () and the first excited state (). Therefore, the atoms can absorb this energy and transition to the state . Statement (a) is incorrect because absorption occurs. Statement (c) is incorrect because the interaction is probabilistic; not all atoms absorb photons simultaneously. Statement (d) is correct because the energy is insufficient to bridge the gap to (), and quantized transitions require specific energies . Thus, statements (b) and (d) are correct.
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