The ratio of the specific heats CP/CV=γ in terms of degrees of freedom (n) is given by:
A
1 + 1/n
B
1 + n/3
C
1 + 2/n
D
1 + n/2
Step-by-Step Solution
Specific Heat at Constant Volume (CV): According to the Law of Equipartition of Energy, for a gas with n degrees of freedom, the molar specific heat at constant volume is given by CV=2nR, where R is the universal gas constant .
Specific Heat at Constant Pressure (CP): Using Mayer's relation for an ideal gas, CP−CV=R. Substituting the value of CV, we get CP=2nR+R=R(2n+1)=R(2n+2).
Ratio of Specific Heats (γ): The ratio is defined as γ=CVCP.
Substituting the expressions:
γ=2nRR(2n+2)=nn+2=1+n2.
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