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The amount of heat energy required to raise the temperature of 1 g of Helium at NTP, from T1T_1 K to T2T_2 K is:

A

32NakB(T2T1)\frac{3}{2} N_a k_B (T_2 - T_1)

B

34NakB(T2T1)\frac{3}{4} N_a k_B (T_2 - T_1)

C

34NakBT2T1\frac{3}{4} N_a k_B \frac{T_2}{T_1}

D

38NakB(T2T1)\frac{3}{8} N_a k_B (T_2 - T_1)

Step-by-Step Solution

  1. Identify the Gas and Moles: Helium (He) is a monoatomic gas. Its molar mass (MM) is 4 g/mol4 \text{ g/mol}. Given mass m=1 gm = 1 \text{ g}. Number of moles n=mM=14 moln = \frac{m}{M} = \frac{1}{4} \text{ mol}.
  2. Identify Specific Heat: For a monoatomic gas, the molar specific heat at constant volume is Cv=32RC_v = \frac{3}{2}R. (Note: While the problem mentions NTP, which often implies constant pressure, the available options match the calculation for constant volume or internal energy change. If calculated at constant pressure, Cp=52RC_p = \frac{5}{2}R, yielding a coefficient of 5/8, which is not an option).
  3. Calculate Heat Energy: The heat energy required (QQ) is given by Q=nCvΔTQ = n C_v \Delta T. Q=(14)×(32R)×(T2T1)=38R(T2T1)Q = \left(\frac{1}{4}\right) \times \left(\frac{3}{2}R\right) \times (T_2 - T_1) = \frac{3}{8} R (T_2 - T_1).
  4. Substitute Constants: The universal gas constant RR is related to the Boltzmann constant (kBk_B) and Avogadro's number (NaN_a) by the equation R=NakBR = N_a k_B. Substituting this into the heat equation: Q=38NakB(T2T1)Q = \frac{3}{8} N_a k_B (T_2 - T_1).
  5. Correction Note: The input text '111 g' is interpreted as a typo for '1 g' based on the mathematical derivation yielding the correct option.
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