The work done on a gas during compression is given by the area under the pressure-volume (P−V) curve (w=−∫PexdV) .
- Isochoric Process: The volume is constant (dV=0), so the work done is zero .
- Isobaric Process: The pressure is constant. The work done is the area of the rectangle under the horizontal line.
- Isothermal vs. Adiabatic:
For an ideal gas, the slope of the adiabatic curve (PVγ=constant) is steeper than that of the isothermal curve (PV=constant) because γ>1. During compression from an initial volume V to V/2, the final pressure attained in an adiabatic process is higher than in an isothermal process (since temperature increases in adiabatic compression but remains constant in isothermal).
- Consequently, the P-V curve for adiabatic compression lies above the isothermal curve, enclosing a larger area.
Therefore, the maximum work is done in the adiabatic compression.