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The value of the coefficient of volume expansion of glycerine is 5×104 K15 \times 10^{-4} \text{ K}^{-1}. The fractional change in the density of glycerine for a rise of 40C40^\circ\text{C} in its temperature is:

A

0.015

B

0.02

C

0.025

D

0.01

Step-by-Step Solution

Let the initial volume be VV and initial density be ρ\rho. Since mass MM remains constant, ρ=MV\rho = \frac{M}{V}. When temperature increases by ΔT\Delta T, the new volume VV' is given by: V=V(1+γΔT)V' = V(1 + \gamma \Delta T) The new density ρ\rho' is: ρ=MV=MV(1+γΔT)=ρ1+γΔT\rho' = \frac{M}{V'} = \frac{M}{V(1 + \gamma \Delta T)} = \frac{\rho}{1 + \gamma \Delta T} The fractional change in density is given by: Δρρ=ρρρ=1ρρ=111+γΔT=γΔT1+γΔT\frac{\Delta \rho}{\rho} = \frac{\rho - \rho'}{\rho} = 1 - \frac{\rho'}{\rho} = 1 - \frac{1}{1 + \gamma \Delta T} = \frac{\gamma \Delta T}{1 + \gamma \Delta T} Since γΔT1\gamma \Delta T \ll 1, we can approximate this as: ΔρργΔT\frac{\Delta \rho}{\rho} \approx \gamma \Delta T Given: γ=5×104 K1\gamma = 5 \times 10^{-4} \text{ K}^{-1} ΔT=40C=40 K\Delta T = 40^\circ\text{C} = 40 \text{ K} Fractional change 5×104×40=200×104=0.020\approx 5 \times 10^{-4} \times 40 = 200 \times 10^{-4} = 0.020

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