The potential energy between two atoms in a molecule is given by , where and are positive constants and is the distance between the atoms. The atoms are in stable equilibrium when:
For stable equilibrium, the net force acting on the particles must be zero, and the potential energy must be at a minimum. The force is related to the potential energy by the equation: Given the potential energy function , we differentiate it with respect to : For equilibrium, the force , which means : To confirm it is a point of stable equilibrium, the second derivative must be positive (indicating a potential energy minimum). Substituting into this derivative yields a positive value, confirming stable equilibrium. Thus, the atoms are in stable equilibrium when .
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