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The potential energy between two atoms in a molecule is given by U(x)=ax12bx6U(x) = \frac{a}{x^{12}} - \frac{b}{x^6}, where aa and bb are positive constants and xx is the distance between the atoms. The atoms are in stable equilibrium when:

A

x=11a5b1x = \sqrt[1]{\frac{11a}{5b}}

B

x=a2b1x = \sqrt[1]{\frac{a}{2b}}

C

x=0x = 0

D

x=2ab1x = \sqrt[1]{\frac{2a}{b}}

Step-by-Step Solution

For stable equilibrium, the net force acting on the particles must be zero, and the potential energy must be at a minimum. The force FF is related to the potential energy U(x)U(x) by the equation: F=dUdxF = -\frac{dU}{dx} Given the potential energy function U(x)=ax12bx6=ax12bx6U(x) = \frac{a}{x^{12}} - \frac{b}{x^6} = ax^{-12} - bx^{-6}, we differentiate it with respect to xx: dUdx=12ax13(6)bx7=12ax13+6bx7\frac{dU}{dx} = -12ax^{-13} - (-6)bx^{-7} = -\frac{12a}{x^{13}} + \frac{6b}{x^7} For equilibrium, the force F=0F = 0, which means dUdx=0\frac{dU}{dx} = 0: 12ax13+6bx7=0-\frac{12a}{x^{13}} + \frac{6b}{x^7} = 0 6bx7=12ax13\frac{6b}{x^7} = \frac{12a}{x^{13}} x6=12a6b=2abx^6 = \frac{12a}{6b} = \frac{2a}{b} x=2abx = \sqrt{\frac{2a}{b}} To confirm it is a point of stable equilibrium, the second derivative d2Udx2\frac{d^2U}{dx^2} must be positive (indicating a potential energy minimum). d2Udx2=156ax1442bx8\frac{d^2U}{dx^2} = 156ax^{-14} - 42bx^{-8} Substituting x6=2abx^6 = \frac{2a}{b} into this derivative yields a positive value, confirming stable equilibrium. Thus, the atoms are in stable equilibrium when x=2abx = \sqrt{\frac{2a}{b}}.

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