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CHEMISTRYElectrochemistryMedium

Zinc can be coated on iron to produce galvanised iron but the reverse is not possible. It is because

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CHEMISTRYElectrochemistryMedium

Find the emf of the cell in which the following reaction takes place at $298\text{ K}$: $Ni(s) + 2Ag^+(0.001\text{ M}) \rightarrow Ni^{2+}(0.001\text{ M}) + 2Ag(s)$ (Given that $E^{\circ}_{cell} = 1.05\text{ V}; \frac{2.303RT}{F} = 0.059$)

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CHEMISTRYElectrochemistryMedium

The pressure of $\text{H}_2$ required to make the potential of $\text{H}_2$-electrode zero in pure water at $298 \text{ K}$ is

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CHEMISTRYAlcohols, Phenols and EthersMedium

Identify the statement that is incorrect regarding chirality:

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CHEMISTRYElectrochemistryMedium

In the electrochemical cell: $\text{Zn}|\text{ZnSO}_4(0.01 \text{ M}) || \text{CuSO}_4(1.0 \text{ M})|\text{Cu}$, the emf of this Daniel cell is $E_1$. When the concentration of $\text{ZnSO}_4$ is changed to $1.0 \text{ M}$ and that of $\text{CuSO}_4$ is changed to $0.01 \text{ M}$, the emf changes to $E_2$. The relationship between $E_1$ and $E_2$ is : (Given, $\frac{RT}{F} = 0.059$)

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CHEMISTRYElectrochemistryMedium

The molar conductance of $\text{NaCl}$, $\text{HCl}$, and $\text{CH}_3\text{COONa}$ at infinite dilution are $126.45$, $426.16$, and $91.0\text{ S cm}^2\text{ mol}^{-1}$ respectively. The molar conductance of $\text{CH}_3\text{COOH}$ at infinite dilution will be:

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CHEMISTRYEquilibriumEasy

Conjugate acid of $\text{NH}_2^-$ is:

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CHEMISTRYAlcohols, Phenols and EthersMedium

A reaction among the following can generate isonitriles as a major product. (A) $\text{R-X} + \text{HCN} \rightarrow$ (B) $\text{R-X} + \text{AgCN} \rightarrow$ (C) $\text{R-X} + \text{KCN} \rightarrow$ (D) $\text{R-X} + \text{NaCN} \xrightarrow{\text{C}_2\text{H}_5\text{OH}/\text{H}_2\text{O}}$ Choose the most appropriate answer from the options given below:

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CHEMISTRYEquilibriumMedium

For the reaction, $CH_4(g) + 2O_2(g) \rightleftharpoons CO_2(g) + 2H_2O(l)$, $\Delta_r H = -170 \text{ kJ mol}^{-1}$. Which of the following statements is not true?

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CHEMISTRYElectrochemistryMedium

In producing chlorine through electrolysis, 100 W power at 125 V is being consumed. The liberation of chlorine per min is: (ECE of chlorine is $0.367 \times 10^{-6} \text{ kg/C}$)

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CHEMISTRYElectrochemistryEasy

Given the following cell reaction: $2\text{Fe}^{3+}\text{(aq)} + 2\text{I}^-\text{(aq)} \rightarrow 2\text{Fe}^{2+}\text{(aq)} + \text{I}_2\text{(aq)}$ $E^\circ_{\text{cell}} = 0.24 \text{ V}$ at $298 \text{ K}$. The standard Gibbs energy $\Delta_r G^\circ$ of the cell reaction is: [Given: $F = 96500 \text{ C mol}^{-1}$]

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CHEMISTRYElectrochemistryMedium

Limiting molar conductivities, for the given solutions, are: $\lambda^0_m(\text{H}_2\text{SO}_4) = x \text{ S cm}^2 \text{ mol}^{-1}$ $\lambda^0_m(\text{K}_2\text{SO}_4) = y \text{ S cm}^2 \text{ mol}^{-1}$ $\lambda^0_m(\text{CH}_3\text{COOK}) = z \text{ S cm}^2 \text{ mol}^{-1}$ From the data given above, it can be concluded that $\lambda^0_m$ in $(\text{S cm}^2 \text{ mol}^{-1})$ for $\text{CH}_3\text{COOH}$ will be:

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CHEMISTRYElectrochemistryMedium

For the disproportionation of copper: $2Cu^+ \rightarrow Cu^{2+} + Cu$, $E^{\circ}$ is: (Given $E^{\circ}$ for $Cu^{2+}/Cu$ is $0.34\text{ V}$ and $E^{\circ}$ for $Cu^{2+}/Cu^+$ is $0.15\text{ V}$)

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CHEMISTRYEquilibriumMedium

Which of the following molecules acts as a Lewis acid?

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CHEMISTRYEquilibriumMedium

Which of the following fluoro-compounds is most likely to behave as a Lewis base?

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CHEMISTRYElectrochemistryMedium

The molar conductance of an electrolyte increases with dilution according to the equation: $\Lambda_m = \Lambda^{\circ}_m - A\sqrt{c}$ Consider the following four statements: A: This equation applies to both strong and weak electrolytes. B: The value of the constant $A$ depends upon the nature of the solvent. C: The value of constant $A$ is the same for both $\text{BaCl}_2$ and $\text{MgSO}_4$. D: The value of constant $A$ is the same for both $\text{BaCl}_2$ and $\text{Mg(OH)}_2$. Which of the above statements are correct?

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CHEMISTRYEquilibriumEasy

The fertilizer which makes the soil acidic is:

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CHEMISTRYEasy

Polyblend, a fine powder of recycled modified plastic, has proved to be a good material for

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CHEMISTRYElectrochemistryMedium

$\Lambda^o_m$ for $\text{NaCl}$, $\text{HCl}$ and $\text{CH}_3\text{COONa}$ are $126.4$, $425.9$, and $91.05\text{ S cm}^2\text{ mol}^{-1}$ respectively. If the conductivity of $0.001028\text{ mol L}^{-1}$ acetic acid solution is $4.95 \times 10^{-5}\text{ S cm}^{-1}$, the degree of dissociation of the acetic acid solution is:

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CHEMISTRYElectrochemistryMedium

For a cell reaction involving a two-electron change, the standard Emf of the cell is found to be $0.295\text{ V}$ at $25^{\circ}\text{C}$. The equilibrium constant of the reaction at $25^{\circ}\text{C}$ will be:

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