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CHEMISTRYThermodynamicsEasy

Based on the following thermochemical equations: (i) $H_{2}O(g) + C(s) ightarrow CO(g) + H_{2}(g); \Delta H = 131 ext{ kJ}$ (ii) $CO(g) + rac{1}{2}O_{2}(g) ightarrow CO_{2}(g); \Delta H = -282 ext{ kJ}$ (iii) $H_{2}(g) + rac{1}{2}O_{2}(g) ightarrow H_{2}O(g); \Delta H = -242 ext{ kJ}$ The value of $X$ for the reaction $C(s) + O_{2}(g) ightarrow CO_{2}(g); \Delta H = X ext{ kJ}$ is [CBSE PMT 1992]:

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CHEMISTRYThermodynamicsEasy

Which of the following equations correctly represents the standard heat of formation (ΔfH°) of methane [IIT JEE (Screening) 1992]?

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CHEMISTRYThermodynamicsMedium

If for a certain reaction $\Delta_r H$ is $30\text{ kJ mol}^{-1}$ at $450\text{ K}$, the value of $\Delta_r S$ (in $\text{J K}^{-1}\text{ mol}^{-1}$) for which the same reaction will be spontaneous at the same temperature is:

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CHEMISTRYThermodynamicsEasy

Equal volumes of two monoatomic gases, A and B, at same temperature and pressure are mixed. The ratio of specific heats ($C_p/C_v$) of the mixture will be:

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CHEMISTRYThermodynamicsMedium

The heat of combustion of carbon to $CO_2$ is -393.5 kJ/mol. The heat released upon the formation of 35.2 g of $CO_2$ from carbon and oxygen gas is:

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CHEMISTRYThermodynamicsMedium

For a sample of perfect gas when its pressure is changed isothermally from $p_i$ to $p_f$, the entropy change is given by:

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CHEMISTRYThermodynamicsMedium

Enthalpy change for the reaction, $4H(g) \rightarrow 2H_2(g)$ is $-869.6 \text{ kJ}$. The dissociation energy of the H-H bond is:

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CHEMISTRYThermodynamicsMedium

What is the entropy change (in J K⁻¹ mol⁻¹) when one mole of ice is converted into water at 0 ºC? (The enthalpy change for the conversion of ice to liquid water is 6.0 kJ mol⁻¹ at 0 ºC)

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CHEMISTRYThermodynamicsMedium

The heat of transition ($\Delta H_t$) of graphite into diamond would be, given the following thermochemical equations: 1. C(graphite) + O$_2$(g) $\rightarrow$ CO$_2$(g); $\Delta H = x$ kJ 2. C(diamond) + O$_2$(g) $\rightarrow$ CO$_2$(g); $\Delta H = y$ kJ

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CHEMISTRYThermodynamicsMedium

Work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from a pressure of 20 atmospheres to a pressure of 10 atmospheres is: (Given: R = 2.0 cal K–1 mol–1)

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CHEMISTRYThermodynamicsEasy

Match List I with List II. List-I (Process) A. Isothermal process B. Isochoric process C. Isobaric process D. Adiabatic process List-II (Conditions) I. No heat exchange II. Carried out at constant temperature III. Carried out at constant volume IV. Carried out at constant pressure Choose the correct answer from the options given below:

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CHEMISTRYThermodynamicsEasy

Which p-V curve among the following depicts the highest amount of work done?

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CHEMISTRYThermodynamicsEasy

Determine $\Delta U$ for the process where, one mole of an ideal gas at $300 \text{ K}$ is expanded isothermally from $1 \text{ L}$ to $10 \text{ L}$ volume: (Use $R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}$)

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CHEMISTRYThermodynamicsMedium

In a closed insulated container a liquid is stirred with a paddle to increase the temperature. The correct option regarding this among the following is:

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ChemistryMedium

Which of the following is not correct about carbon monoxide?

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ChemistryMedium

Anisole on cleavage with HI gives

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CHEMISTRYEasy

Which of the following reactions is the metal displacement reaction? Choose the right option.

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CHEMISTRYEasy

Given below are two statements : Statement I : Aspirin and Paracetamol belong to the class of narcotic analgesics. Statement II : Morphine and Heroin are non-narcotic analgesics. In the light of the above statements, choose the correct answer from the options given below.

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CHEMISTRYMedium

The correct structure of 2, 6-Dimethyl-dec-4-ene is

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CHEMISTRYEasy

$CH_3CH_2COO^- Na^+ \xrightarrow[\text{Heat}]{\text{NaOH, ?}} CH_3CH_3 + Na_2CO_3$. Consider the above reaction and identify the missing reagent/chemical.

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