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NEET CHEMISTRYElectrochemistryMedium

Question

The correct value of cell potential in volts for the reaction that occurs when the following two half cells are connected, is: Fe2+(aq)+2eFe(s) ;\E=0.44 VFe^{2+}(aq) + 2e^- \rightarrow Fe(s) \ ; \E^{\circ} = -0.44\text{ V} Cr2O72(aq)+14H++6e2Cr3++7H2O ;\E=+1.33 VCr_2O_7^{2-}(aq) + 14H^+ + 6e^- \rightarrow 2Cr^{3+} + 7H_2O \ ; \E^{\circ} = +1.33\text{ V}

A

+1.77 V

B

+2.65 V

C

+0.01 V

D

+0.89 V

Step-by-Step Solution

To determine the correct cell potential (EcellE^{\circ}_{cell}), we identify the cathode and the anode based on their standard reduction potentials (EE^{\circ}). The half-cell with the higher standard reduction potential will undergo reduction and act as the cathode. The half-cell with the lower standard reduction potential will undergo oxidation and act as the anode. Given: ECr2O72/Cr3+=+1.33 VE^{\circ}_{Cr_2O_7^{2-}/Cr^{3+}} = +1.33\text{ V} (Cathode) EFe2+/Fe=0.44 VE^{\circ}_{Fe^{2+}/Fe} = -0.44\text{ V} (Anode)

The standard cell potential is calculated as: Ecell=EcathodeEanodeE^{\circ}_{cell} = E^{\circ}_{cathode} - E^{\circ}_{anode} Ecell=1.33 V(0.44 V)E^{\circ}_{cell} = 1.33\text{ V} - (-0.44\text{ V}) Ecell=1.33+0.44=+1.77 VE^{\circ}_{cell} = 1.33 + 0.44 = +1.77\text{ V}

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Electrochemistry. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYElectrochemistrycorrectpotentialreactionoccursfollowing

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