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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which of the following compounds has a higher hydration energy than the lattice energy?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The correct order of dipole moments for molecules NH$$_3$$, H$$_2$$S, CH$$_4$$ and HF is:

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CHEMISTRYChemical KineticsEasy

The half-life period of a first-order reaction is 1386 s. The specific rate constant of the reaction is:

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CHEMISTRYChemical KineticsMedium

$^{235}_{92}U$ nucleus absorbs a neutron and disintegrates into $^{139}_{54}Xe$, $^{94}_{38}Sr$ and $x$. The product $x$ is:

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CHEMISTRYChemical KineticsMedium

In the reaction, $\text{BrO}_3^-(aq) + 5\text{Br}^-(aq) + 6\text{H}^+(aq) \rightarrow 3\text{Br}_2(l) + 2\text{H}_2\text{O}(l)$ The rate of appearance of bromine ($\text{Br}_2$) is related to rate of disappearance of bromide ions as following:

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CHEMISTRYChemical KineticsEasy

The half-life for a zero-order reaction having 0.02 M initial concentration of reactant is 100 s. The rate constant (in mol L⁻¹ s⁻¹) for the reaction is:

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CHEMISTRYAlcohols, Phenols and EthersEasy

The $\text{-OH}$ group of an alcohol or the carboxylic acid can be replaced by $\text{-Cl}$ using:

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CHEMISTRYChemical KineticsEasy

A reaction having equal energies of activation for forward and reverse reaction has:

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CHEMISTRYElectrochemistryMedium

In the silver plating of copper, $K[Ag(CN)_2]$ is used instead of $AgNO_3$. The reason is:

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CHEMISTRYEquilibriumMedium

Consider the following reaction: $\text{A}_2(g) + \text{B}_2(g) \rightleftharpoons 2\text{AB}(g)$. At equilibrium, the concentrations of $[\text{A}_2] = 3.0 \times 10^{–3} \text{ M}$; $[\text{B}_2] = 4.2 \times 10^{–3} \text{ M}$ and $[\text{AB}] = 2.8 \times 10^{–3} \text{ M}$. The value of $K_c$ for the above-given reaction in a sealed container at $527^\circ\text{C}$ is:

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CHEMISTRYEquilibriumEasy

Amongst the given options, which of the following molecules/ions acts as a Lewis acid?

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CHEMISTRYAlcohols, Phenols and EthersMedium

$\text{CH}_3\text{CH}_2\text{CHCl}_2$ upon reaction with $\text{NaNH}_2$ gives:

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CHEMISTRYEquilibriumMedium

Boric acid is an acid because its molecule

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CHEMISTRYEquilibriumMedium

The following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations. pH of which one of them will be equal to 1?

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CHEMISTRYEquilibriumMedium

The tendency of $BF_3$, $BCl_3$ and $BBr_3$ to behave as Lewis acid decreases in the sequence:

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CHEMISTRYAlcohols, Phenols and EthersMedium

The end product in the below-mentioned reaction is: $\text{H}_3\text{C-Br} \xrightarrow{\text{KCN}} \text{A} \xrightarrow{\text{H}_3\text{O}^+} \text{B} \xrightarrow{\text{LiAlH}_4\text{, Ether}} \text{C}$

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CHEMISTRYElectrochemistryMedium

Molar conductivities ($\Lambda^{\circ}_m$) at infinite dilution of $NaCl$, $HCl$, and $CH_3COONa$ are $126.4$, $425.9$, and $91.0\text{ S cm}^2\text{ mol}^{-1}$ respectively. $\Lambda^{\circ}_m$ for $CH_3COOH$ will be:

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CHEMISTRYElectrochemistryMedium

The weight of silver (atomic weight = $108$) displaced by a quantity of electricity which displaces $5600 \text{ mL}$ of $\text{O}_2$ at STP will be :

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CHEMISTRYEquilibriumEasy

A compound $\text{BA}_2$ has $K_{sp} = 4 \times 10^{-12}$. Solubility of this compound will be:

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CHEMISTRYElectrochemistryEasy

At $25^\circ\text{C}$, molar conductance of $0.1 \text{ molar}$ aqueous solution of ammonium hydroxide is $9.54 \text{ ohm}^{-1}\text{cm}^2\text{mol}^{-1}$ and at infinite dilution, its molar conductance is $238 \text{ ohm}^{-1}\text{cm}^2 \text{mol}^{-1}$. The degree of ionization of ammonium hydroxide at the same concentration and temperature is:

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