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NEET CHEMISTRYAldehydes, Ketones and Carboxylic AcidsEasy

Question

Mark the name of the reaction associated with the following conversion:

A

Stephen reaction

B

Gattermann-Koch reaction

C

Etard reaction

D

Rosenmund reaction

Step-by-Step Solution

The Rosenmund reaction is a specific hydrogenation process where an acyl chloride (acid chloride) is converted into an aldehyde. This reduction is carried out using hydrogen gas (H2H_2) in the presence of a catalyst, palladium supported on barium sulphate (Pd/BaSO4Pd/BaSO_4). The reaction scheme is generally represented as: RCOCl+H2Pd/BaSO4RCHO+HClR-COCl + H_2 \xrightarrow{Pd/BaSO_4} R-CHO + HCl

Other options refer to different preparations:

  • Stephen reaction: Reduction of nitriles to aldehydes using SnCl2/HClSnCl_2/HCl.
  • Gattermann-Koch reaction: Formylation of benzene derivatives using COCO and HClHCl with AlCl3AlCl_3.
  • Etard reaction: Oxidation of the methyl group in toluene to an aldehyde using chromyl chloride (CrO2Cl2CrO_2Cl_2).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Aldehydes, Ketones and Carboxylic Acids. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAldehydes, Ketones and Carboxylic Acidsreactionassociatedfollowingconversion

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