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CHEMISTRYThe d-and f-Block ElementsMedium

Gadolinium has a low value of third ionisation enthalpy because of:

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CHEMISTRYAlcohols, Phenols and EthersMedium

The most acidic compound among the following is:

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CHEMISTRYThe d-and f-Block ElementsMedium

The d-electron configurations of Cr²⁺, Mn²⁺, Fe²⁺ and Ni²⁺ are 3d⁴, 3d⁵, 3d⁶ and 3d⁸ respectively. Which one of the following aqua complexes will exhibit the minimum paramagnetic behaviour? (At. No. Cr = 24, Mn = 25, Fe = 26, Ni = 28)

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CHEMISTRYThe d-and f-Block ElementsMedium

The electronic configurations of $\text{Eu}$ (Atomic no. $63$), $\text{Gd}$ (Atomic no. $64$), and $\text{Tb}$ (Atomic no. $65$) are, respectively:

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CHEMISTRYThe d-and f-Block ElementsMedium

Match List-I with List-II: **List-I (Element)** (A) Fe (B) V (C) Mn (D) Ti **List-II (Most Common oxidation state/s)** (I) +2, +7 (II) +3, +2 (III) +4 (IV) +5 Choose the correct answer from the options given below:

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CHEMISTRYAlcohols, Phenols and EthersMedium

Iodoform reaction is given by: (a) $CH_3CH_2OH$ (b) $CH_3COCH_3$ (c) [Compound Missing] (d) $CH_3OH$

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CHEMISTRYThe d-and f-Block ElementsEasy

A pair among the following that have the same size is:

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CHEMISTRYThe d-and f-Block ElementsMedium

When copper is heated with conc. $\text{HNO}_3$ it produces:

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CHEMISTRYThe d-and f-Block ElementsMedium

Compound 'A' in acidic medium does not give a precipitate with $H_2S$ but in $NH_4OH$ medium gives a precipitate. Compound 'A' is:

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CHEMISTRYAlcohols, Phenols and EthersMedium

The IUPAC name of the product that formed in the following chemical reaction is: Acetone $\xrightarrow{\text{(i) } C_2H_5MgBr, \text{ dry Ether}}$ $\xrightarrow{\text{(ii) } H_2O, H^+}$ Product

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CHEMISTRYThe d-and f-Block ElementsMedium

The basic character of the transition metal monoxides follows the order: (Atomic nos. Ti = 22, V = 23, Cr = 24, Fe = 26)

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CHEMISTRYAlcohols, Phenols and EthersMedium

Match the reagents (List-I) with the products (List-II) obtained from phenol and select the correct option. **List-I (Reagents)** (A) (i) NaOH, (ii) CO₂, (iii) H⁺ (B) (i) Aqueous NaOH + CHCl₃, (ii) H⁺ (C) Zn dust, Δ (D) Na₂Cr₂O₇, H₂SO₄ **List-II (Products)** (I) Benzoquinone (II) Benzene (III) Salicylaldehyde (IV) Salicylic acid

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CHEMISTRYAldehydes, Ketones and Carboxylic AcidsMedium

A yellow precipitate with iodine and alkali is given by:

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CHEMISTRYAldehydes, Ketones and Carboxylic AcidsMedium

Reaction of a carbonyl compound with one of the following reagents involves nucleophilic addition followed by the elimination of water. The reagent is:

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CHEMISTRYThe d-and f-Block ElementsEasy

Which of the following elements can combine with chlorine to form more than one binary compound?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The pair of electrons in the given carbanion, $\text{CH}_3\text{C}\equiv\text{C}^-$, is present in which of the following orbitals?

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CHEMISTRYP Block ElementsMedium

The number of carbon atoms per unit cell of diamond unit cell is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which of the following pairs of ions are isoelectronic and isostructural?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which orbital does the additional electron occupy when $O_{2}$ is converted to the $O_{2}^{-}$ ion?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

Identify the incorrect statement among the following:

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