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CHEMISTRYMedium

Identify the incorrect statement related to $PCl_5$ from the following:

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CHEMISTRYHaloalkanes and HaloarenesMedium

Which one is the most reactive toward $S_N1$ reaction?

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CHEMISTRYHydrocarbonsMedium

The compound that will react most readily with gaseous bromine has the formula:

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CHEMISTRYHaloalkanes and HaloarenesMedium

Which of the following reactions cannot form new carbon-carbon bonds?

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CHEMISTRYHaloalkanes and HaloarenesMedium

The compound that will undergo $\text{S}_\text{N}1$ reaction with the fastest rate is:

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CHEMISTRYEquilibriumHard

Consider the following reaction in a sealed vessel at equilibrium: $2\text{NO}(g) \rightleftharpoons \text{N}_2(g) + \text{O}_2(g)$ [Given: $[\text{N}_2]=3.0 \times 10^{-3}\text{ M}$, $[\text{O}_2]=4.2 \times 10^{-3}\text{ M}$ and $[\text{NO}]=2.8 \times 10^{-3}\text{ M}$] If $0.1\text{ mol L}^{-1}$ of $\text{NO}(g)$ is taken in a closed vessel, what will be the degree of dissociation ($\alpha$) of $\text{NO}(g)$ at equilibrium?

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CHEMISTRYHaloalkanes and HaloarenesMedium

In which of the following compounds, the C—Cl bond ionization shall give the most stable carbonium ion?

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CHEMISTRYHaloalkanes and HaloarenesMedium

What are the major products A and B formed in the following reaction sequence?

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CHEMISTRYHydrocarbonsMedium

Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction?

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CHEMISTRYHydrocarbonsEasy

The molecule among the following that has the hybridization $sp^2, sp^2, sp, \text{ and } sp$ from left to right atoms is:

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CHEMISTRYHydrocarbonsMedium

2,3-dimethyl-2-butene can be prepared by heating which of the following compounds with a strong acid?

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CHEMISTRYHydrocarbonsMedium

In the following reaction, $$ CH_3-C \equiv CH \xrightarrow[873 K]{\text{Red hot iron tube}} A $$ The number of sigma ($\sigma$) bonds present in the product $A$ is:

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CHEMISTRYHydrocarbonsMedium

The compound obtained by addition of water to an alkyne having more than two carbons, in the presence of $\text{HgSO}_4$ and dilute $\text{H}_2\text{SO}_4$ at $333\text{ K}$, is:

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CHEMISTRYHydrocarbonsMedium

Given compounds are as follows: (I) (II) (III). The enthalpy of hydrogenation of these compounds will be in the order as-

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CHEMISTRYHydrocarbonsEasy

Given below are two statements: Statement I: The boiling point of three isomeric pentanes follows the order, n-Pentane > Isopentane > Neopentane. Statement II: When branching increases, the molecule attains the shape of a sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point.

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CHEMISTRYHydrocarbonsEasy

The alkane that gives only one monochloro product on chlorination with $Cl_2$ in presence of diffused sunlight is:

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CHEMISTRYHydrocarbonsMedium

Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to a gaseous hydrocarbon containing less than four carbon atoms. The formula of (A) is:

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CHEMISTRYHydrocarbonsMedium

An alkene on ozonolysis gives methanal as one of the products. Its structure is:

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CHEMISTRYHydrocarbonsMedium

The increasing order of electrophilic substitution for the following compounds (structures missing) is:

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CHEMISTRYHydrocarbonsMedium

For the given reaction: 'P' is:

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