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CHEMISTRYMedium

Right option for the number of tetrahedral and octahedral voids in hexagonal primitive unit cell are :

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CHEMISTRYThermodynamicsEasy

Which of the following compounds will absorb the maximum quantity of heat when dissolved in the same amount of water? The heats of solution ($\Delta H_{sol}$) of these compounds at $25^{\circ}C$ in kJ/mol of each solute are given in brackets [AMU (Engg.) 2000]:

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CHEMISTRYThermodynamicsMedium

A gas is allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy $\Delta U$ of the gas in joules will be:

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CHEMISTRYThermodynamicsEasy

Enthalpy of combustion of carbon to carbon dioxide is −390.0 kJ mol⁻¹. The amount of heat released when 35.0 g of CO2 is formed from the reaction of carbon and dioxygen gas, is:

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CHEMISTRYThermodynamicsMedium

Heat of combustion $\Delta H^\circ$ for $C(s)$, $H_2(g)$ and $CH_4(g)$ are $-94$, $-68$ and $-213\text{ Kcal/mol}$. $\Delta H^\circ$ for $C(s) + 2H_2(g) \rightarrow CH_4 (g)$ is:

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CHEMISTRYThermodynamicsMedium

Consider the following processes: $\frac{1}{2}\text{A} \rightarrow \text{B}; \Delta H = +150\text{ kJ/mol}$ $3\text{B} \rightarrow 2\text{C} + \text{D}; \Delta H = -125\text{ kJ/mol}$ $\text{E} + \text{A} \rightarrow 2\text{D}; \Delta H = +350\text{ kJ/mol}$ For $\text{B} + \text{D} \rightarrow \text{E} + 2\text{C}, \Delta H$ will be:

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CHEMISTRYThermodynamicsMedium

The bond energy of H—H and Cl—Cl is $430 \text{ kJ mol}^{-1}$ and $240 \text{ kJ mol}^{-1}$ respectively and $\Delta_f H$ for HCl is $-90 \text{ kJ mol}^{-1}$. The bond enthalpy of HCl is:

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CHEMISTRYThermodynamicsMedium

The standard enthalpy of vaporisation $\Delta_{vap}H^{\circ}$ for water at $100^{\circ}\text{C}$ is $40.66 \text{ kJ mol}^{-1}$. The internal energy of vaporisation of water at $100^{\circ}\text{C}$ (in $\text{kJ mol}^{-1}$) is: (Assume water vapour to behave like an ideal gas)

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CHEMISTRYThermodynamicsEasy

A process among the following shows decrease in entropy is :

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CHEMISTRYMedium

What is the IUPAC name of the organic compound formed in the following chemical reaction? Acetone $\xrightarrow[(ii) H_2O, H^+]{(i) C_2H_5MgBr, dry Ether}$ Product

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CHEMISTRYThermodynamicsMedium

The work done when $1 \text{ mole}$ of gas expands reversibly and isothermally from a pressure of $5 \text{ atm}$ to $1 \text{ atm}$ at $300 \text{ K}$ is: [Given: $\log 5 = 0.6989$ and $R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}$]

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CHEMISTRYMedium

The molar conductivity of 0.007 M acetic acid is 20 S cm$^2$ mol$^{-1}$. What is the dissociation constant of acetic acid? Choose the correct option. $\left[ \Lambda_{H^+}^\circ = 350 \text{ S cm}^2 \text{ mol}^{-1}, \Lambda_{CH_3COO^-}^\circ = 50 \text{ S cm}^2 \text{ mol}^{-1} \right]$

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CHEMISTRYMedium

Identify the compound that will react with Hinsberg's reagent to give a solid which dissolves in alkali.

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CHEMISTRYMedium

The slope of Arrhenius plot $\left( \ln k \text{ v/s } \frac{1}{T} \right)$ of first order reaction is $-5 \times 10^3 \text{K}$. The value of $E_a$ of the reaction is. Choose the correct option for your answer. [Given $R = 8.314 \text{ JK}^{-1}\text{mol}^{-1}$]

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CHEMISTRYHard

The intermediate compound 'X' in the following chemical reaction is:

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CHEMISTRYMedium

Which of the following molecules is non-polar in nature?

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ChemistryMedium

Identify the correct statements from the following: (a) $CO_2(g)$ is used as refrigerant for ice-cream and frozen food. (b) The structure of $C_{60}$ contains twelve six carbon rings and twenty five carbon rings. (c) ZSM-5, a type of zeolite, is used to convert alcohols into gasoline. (d) CO is colorless and odourless gas.

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CHEMISTRYEquilibriumMedium

Boric acid is an acid because its molecule

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CHEMISTRYBiomoleculesEasy

Deficiency of vitamin B1 causes the disease:

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CHEMISTRYAminesMedium

Given below are two statements: Statement I: Aniline does not undergo Friedel-Crafts alkylation reaction. Statement II: Aniline cannot be prepared through Gabriel synthesis.

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