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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

A diatomic molecule, among the following species, that only has $\pi$ bonds according to the Molecular Orbital Theory (MOT) is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The number of unpaired electrons in a paramagnetic diatomic molecule of an element with atomic number 16 is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

The correct state of hybridisation of C2, C3, C5 and C6 of the hydrocarbon $$ \overset{1}{\text{HC}} \equiv \overset{2}{\text{C}} - \overset{3}{\text{CH}}_2 - \overset{4}{\text{CH}} = \overset{5}{\text{CH}} - \overset{6}{\text{CH}}_3 $$ is in the sequence:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

Consider the following List-I and List-II: **List-I (Molecule)** (a) $PCl_{5}$ (b) $SF_{6}$ (c) $BeCl_{2}$ (d) $NH_{3}$ **List-II (Shape or geometry)** (i) Trigonal planar (ii) Octahedral (iii) Linear (iv) Trigonal pyramidal Identify the **wrong** match from the given pairs:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

Predict the correct order among the following.

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The pair of electrons in the given carbanion, $\text{CH}_3\text{C}\equiv\text{C}^-$, is present in which of the following orbitals?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

An isostructural compound with $XeF_2$ among the following is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which one of the following bonds produces a solid that reflects light in the visible region and whose electrical conductivity decreases with temperature and has a high melting point?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

In which of the following pairs of molecules/ions, the central atoms have $sp^2$ hybridization?

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CHEMISTRYMedium

Which of the following diatomic molecular species has only $\pi$ bonds according to Molecular Orbital Theory?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which of the two ions from the list given below have the geometry that is explained by the same hybridisation of orbitals, $NO_2^-$, $NO_3^-$, $NH_2^-$, $NH_4^+$, $SCN^-$?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which of the following has the minimum bond length?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them.

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CHEMISTRYEasy

The mixture that forms maximum boiling azeotrope is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

A molecule that cannot exist is:

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CHEMISTRYMedium

The manganate and permanganate ions are tetrahedral, due to :

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

Which of the following is a paramagnetic compound?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

Match the following oxides with their nature: **Column I** (a) CO (b) BaO (c) Al₂O₃ (d) Cl₂O₇ **Column II** (i) Basic (ii) Neutral (iii) Acidic (iv) Amphoteric

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

Which of the following species has a bond angle of 120$$^\circ$$?

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The correct bond order in the following species is:

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