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CHEMISTRYElectrochemistryEasy

The conductivity of centimolar solution of KCl at $25^{\circ}\text{C}$ is $0.0210\text{ ohm}^{–1}\text{ cm}^{–1}$ and the resistance of the cell containing the solution at $25^{\circ}\text{C}$ is $60\text{ ohm}$. The value of the cell constant is:

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CHEMISTRYEquilibriumMedium

Given the following two reactions: $A + B \rightleftharpoons C + D$, with equilibrium constant $K_1$ $E + F \rightleftharpoons G + H$, with equilibrium constant $K_2$ What is the equilibrium constant for the reaction $C + D + E + F \rightleftharpoons A + B + G + H$?

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CHEMISTRYEquilibriumMedium

For the equilibrium $2\text{NOCl}(g) \rightleftharpoons 2\text{NO}(g) + \text{Cl}_2(g)$ the value of the equilibrium constant is $3.0 \times 10^{-6}$ at $1000\text{ K}$. Find $K_p$ for the reaction at this temperature (Given $R = 8.314\text{ J K}^{-1}\text{mol}^{-1}$):

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CHEMISTRYEquilibriumMedium

The hydrogen ion concentration of a $10^{-8}\text{ M}$ HCl aqueous solution at 298 K ($K_w = 10^{-14}$) is:

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CHEMISTRYEquilibriumMedium

A buffer solution is prepared in which the concentration of $NH_3$ is 0.30 M and the concentration of $NH_4^+$ is 0.20 M. If the equilibrium constant, $K_b$ for $NH_3$ equals $1.8 \times 10^{-5}$, then what is the pH of this solution? ($\log 1.8 = 0.25$; $\log 0.67 = -0.176$)

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CHEMISTRYEquilibriumMedium

The solubility of $BaSO_4$ in water is $2.42 \times 10^{-3} \text{ g L}^{-1}$ at $298 \text{ K}$. The value of the solubility product will be: (Molar mass of $BaSO_4 = 233 \text{ g mol}^{-1}$)

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CHEMISTRYHydrocarbonsMedium

HCl with an alkene X reacts in accordance with Markovnikov’s rule to give 1-Chloro-1-methylcyclohexane. The structure of alkene (X) is:

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CHEMISTRYMedium

Under isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is (Given that 1 L bar = 100 J)

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CHEMISTRYEquilibriumMedium

For a given exothermic reaction, $K_p$ and $K_p'$ are the equilibrium constants at temperatures $T_1$ and $T_2$ respectively. Assuming that the heat of reaction is constant in the temperature range between $T_1$ and $T_2$, it is readily observed that: (Assume $T_2 > T_1$)

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CHEMISTRYEasy

Which of the following is an amphoteric hydroxide?

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CHEMISTRYEquilibriumMedium

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

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CHEMISTRYHydrocarbonsMedium

In the following reaction, What will be the major product?

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CHEMISTRYHaloalkanes and HaloarenesEasy

$\text{CCl}_2\text{F}_2$ is one of the most common haloalkanes used in industries. The reaction through which it is manufactured from tetrachloromethane is called:

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CHEMISTRYEquilibriumMedium

The equilibrium concentration of the species in the reaction $\text{A} + \text{B} \rightleftharpoons \text{C} + \text{D}$ are $2$, $3$, $10$ and $6\text{ mol L}^{-1}$, respectively at $300\text{ K}$. $\Delta G^\circ$ for the reaction is: ($R = 2\text{ cal/mol K}$)

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CHEMISTRYEquilibriumMedium

$K_p$ for the following reaction is $3.0$ at $1000\text{ K}$. $\text{CO}_2(g) + \text{C}(s) \rightleftharpoons 2\text{CO}(g)$ The value of $K_c$ for the reaction at the same temperature is: (Given: $R = 0.083\text{ L bar K}^{-1} \text{mol}^{-1}$)

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CHEMISTRYEquilibriumMedium

The dissociation constants for acetic acid and HCN at $25^\circ \text{C}$ are $1.5 \times 10^{-5}$ and $4.5 \times 10^{-10}$, respectively. The equilibrium constant for the equilibrium, $CN^- + CH_3COOH \rightleftharpoons HCN + CH_3COO^-$ would be:

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CHEMISTRYHaloalkanes and HaloarenesEasy

Which of the following is the most preferred method for preparing pure alkyl chlorides from alcohols?

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CHEMISTRYHaloalkanes and HaloarenesMedium

Identify the statement that is incorrect regarding chirality:

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CHEMISTRYEquilibriumMedium

What is the $[OH^-]$ in the final solution prepared by mixing $20.0 \text{ mL}$ of $0.050 \text{ M}$ HCl with $30.0 \text{ mL}$ of $0.10 \text{ M } Ba(OH)_2$?

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CHEMISTRYHaloalkanes and HaloarenesMedium

$\text{C}_6\text{H}_5\text{CH}_2\text{Br} \xrightarrow[2.\text{ H}_3\text{O}^+]{1.\text{ Mg, Ether}} \text{X}$ The product 'X' in the above reaction is:

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