back to directory
NEET CHEMISTRYSome Basic Concepts of ChemistryMedium

Question

A mixture of 2.3 g2.3 \text{ g} formic acid and 4.5 g4.5 \text{ g} oxalic acid is treated with conc. H2SO4\text{H}_2\text{SO}_4. The evolved gaseous mixture is passed through KOH\text{KOH} pellets. Weight (in g) of the remaining product at STP will be:

A

1.4

B

3

C

2.8

D

4.4

Step-by-Step Solution

Formic acid (HCOOH\text{HCOOH}) and oxalic acid (H2C2O4\text{H}_2\text{C}_2\text{O}_4) undergo dehydration in the presence of concentrated H2SO4\text{H}_2\text{SO}_4.

  1. Dehydration of formic acid: HCOOHconc. H2SO4H2O+CO\text{HCOOH} \xrightarrow{\text{conc. H}_2\text{SO}_4} \text{H}_2\text{O} + \text{CO} Molar mass of HCOOH=46 g mol1\text{HCOOH} = 46 \text{ g mol}^{-1}. Moles of HCOOH=2.3 g46 g mol1=0.05 mol\text{HCOOH} = \frac{2.3 \text{ g}}{46 \text{ g mol}^{-1}} = 0.05 \text{ mol}. Thus, 0.05 mol0.05 \text{ mol} of CO\text{CO} is produced.

  2. Dehydration of oxalic acid: H2C2O4conc. H2SO4H2O+CO+CO2\text{H}_2\text{C}_2\text{O}_4 \xrightarrow{\text{conc. H}_2\text{SO}_4} \text{H}_2\text{O} + \text{CO} + \text{CO}_2 Molar mass of H2C2O4=90 g mol1\text{H}_2\text{C}_2\text{O}_4 = 90 \text{ g mol}^{-1} . Moles of H2C2O4=4.5 g90 g mol1=0.05 mol\text{H}_2\text{C}_2\text{O}_4 = \frac{4.5 \text{ g}}{90 \text{ g mol}^{-1}} = 0.05 \text{ mol}. Thus, 0.05 mol0.05 \text{ mol} of CO\text{CO} and 0.05 mol0.05 \text{ mol} of CO2\text{CO}_2 are produced.

Total moles of CO\text{CO} evolved =0.05+0.05=0.1 mol= 0.05 + 0.05 = 0.1 \text{ mol}. Total moles of CO2\text{CO}_2 evolved =0.05 mol= 0.05 \text{ mol}.

When the gaseous mixture is passed through KOH\text{KOH} pellets, CO2\text{CO}_2 is absorbed by KOH\text{KOH} to form K2CO3\text{K}_2\text{CO}_3. The remaining gaseous product is only CO\text{CO}. Weight of the remaining product (CO\text{CO}) =Moles×Molar mass= \text{Moles} \times \text{Molar mass} Weight of CO=0.1 mol×28 g mol1=2.8 g\text{CO} = 0.1 \text{ mol} \times 28 \text{ g mol}^{-1} = 2.8 \text{ g}.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Some Basic Concepts of Chemistry. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYSome Basic Concepts of Chemistrymixtureformicoxalictreatedtexthtextso

More Some Basic Concepts of Chemistry Questions

View all

At S.T.P. the density of $\text{CCl}_4$ vapour in $\text{g/L}$ will be nearest to:

A.$6.84$
B.$3.42$
C.$10.26$
D.$4.57$
MediumSolve

Calculate the mass of 95% pure $CaCO_3$ that will be required to neutralize 50 mL of 0.5 M HCl solution according to the following reaction: $$ CaCO_3(s) + 2HCl(aq) \rightarrow CaCl_2(aq) + CO_2(g) + 2H_2O(l) $$ [Calculate up to the second place of decimal point]

A.9.50 g
B.1.25 g
C.1.32 g
D.3.65 g
MediumSolve

The molar mass of a compound (X), whose $2.6 \text{ mol}$ weighs $312 \text{ g}$, is:

A.312 g mol⁻¹
B.120 g mol⁻¹
C.60 g mol⁻¹
D.811.2 g mol⁻¹
EasySolve

Calculate the mole fraction of the solute in a $1.00 \text{ m}$ aqueous solution.

A.0.177
B.0.771
C.0.0534
D.0.0177
MediumSolve

A compound X contains 32% of A, 20% of B and remaining percentage of C. Then, the empirical formula of X is: (Given atomic mass of A = 64; B = 40; C = 32 u)

A.ABC₃
B.AB₂C₂
C.ABC₄
D.A₂BC₂
EasySolve

When $50\text{ mL}$ of a $16.9\%\text{ (w/v)}$ solution of $\text{AgNO}_3$ is mixed with $50\text{ mL}$ of $5.8\%\text{ (w/v) NaCl}$ solution, then the mass of precipitate formed is: ($\text{Ag} = 107.8$, $\text{N} = 14$, $\text{O} = 16$, $\text{Na} = 23$, $\text{Cl} = 35.5$)

A.$28\text{ g}$
B.$3.5\text{ g}$
C.$7\text{ g}$
D.$14\text{ g}$
MediumSolve

The density of a $2 \text{ M}$ aqueous solution of $NaOH$ is $1.28 \text{ g/cm}^3$. The molality of the solution is: [molecular mass of $NaOH = 40 \text{ g mol}^{-1}$]

A.$1.20 \text{ m}$
B.$1.56 \text{ m}$
C.$1.67 \text{ m}$
D.$1.32 \text{ m}$
MediumSolve

How many moles of lead (II) chloride will be formed from a reaction between $6.5\text{ g}$ of $\text{PbO}$ and $3.2\text{ g}$ of $\text{HCl}$?

A.$0.044$
B.$0.333$
C.$0.011$
D.$0.029$
MediumSolve

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →