back to directory
NEET CHEMISTRYHydrocarbonsMedium

Question

Compound 'A' on chlorination gives compound 'B'. 'B' reacts with alc. KOH to give gas 'C' which decolorizes Baeyer reagent. Ozonolysis of compound 'C' gives only HCHO compound. Compound 'A' is:

A

C2H6\text{C}_2\text{H}_6

B

C2H4\text{C}_2\text{H}_4

C

C4H10\text{C}_4\text{H}_{10}

D

C2H5Cl\text{C}_2\text{H}_5\text{Cl}

Step-by-Step Solution

Let us work backwards from the final product to identify compound 'A':

  1. Ozonolysis of compound 'C' gives only methanal (HCHO\text{HCHO}), which indicates that 'C' is a symmetrical alkene with a double bond at the terminal carbon atoms. Therefore, 'C' must be ethene (CH2=CH2\text{CH}_2=\text{CH}_2) .
  2. Ethene ('C') is a gas that decolourises Baeyer's reagent (cold, dilute aqueous KMnO4\text{KMnO}_4), confirming the presence of a double bond .
  3. Compound 'C' (ethene) is formed by the reaction of compound 'B' with alcoholic KOH. This is a dehydrohalogenation (β\beta-elimination) reaction. Thus, 'B' must be an alkyl halide, specifically chloroethane (C2H5Cl\text{C}_2\text{H}_5\text{Cl}) .
  4. Compound 'B' (chloroethane) is formed by the chlorination of compound 'A'. Therefore, 'A' must be the corresponding alkane, which is ethane (C2H6\text{C}_2\text{H}_6) .

The series of reactions is: C2H6Cl2/hνC2H5Clalc. KOHC2H4O3,Zn/H2O2HCHO\text{C}_2\text{H}_6 \xrightarrow{\text{Cl}_2/h\nu} \text{C}_2\text{H}_5\text{Cl} \xrightarrow{\text{alc. KOH}} \text{C}_2\text{H}_4 \xrightarrow{\text{O}_3, \text{Zn}/\text{H}_2\text{O}} 2\text{HCHO}

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Hydrocarbons. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYHydrocarbonscompoundchlorinationcompoundreactsdecolorizes

More Hydrocarbons Questions

View all

Phenylacetylene undergoes a reaction with dilute $\text{H}_2\text{SO}_4$ in the presence of $\text{HgSO}_4$ to yield:

A.Option 1 (Structure missing)
B.Option 2 (Structure missing)
C.Option 3 (Structure missing)
D.Option 4 (Structure missing)
MediumSolve

The reaction among the following that proceeds through an electrophilic substitution reaction is:

A.(Option 1 Structure Missing)
B.(Option 2 Structure Missing)
C.4
D.(Option 4 Structure Missing)
EasySolve

The order of decreasing reactivity towards an electrophilic reagent for the following compounds is: (i) Benzene (ii) Toluene (iii) Chlorobenzene (iv) Phenol

A.(i) > (ii) > (iii) > (iv)
B.(ii) > (iv) > (i) > (iii)
C.(iv) > (iii) > (ii) > (i)
D.(iv) > (ii) > (i) > (iii)
MediumSolve

X and Y in the above-mentioned reaction are respectively:

A.X = 2–Butyne; Y = 3–Hexyne
B.X = 2-Butyne; Y = 2-Hexyne
C.X = 1-Butyne; Y = 2-Hexyne
D.X = 1-Butyne; Y = 3–Hexyne
MediumSolve

Match the bond line structures of hydrocarbons given in List-I with the corresponding boiling points given in List-II. List-II (Boiling point in K): (i) 300.9 (ii) 282.5 (iii) 309.1 (iv) 341.9 Choose the correct answer from the options given below:

A.(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
B.(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
C.(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
D.(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
MediumSolve

The dihedral angle of the least stable conformer of ethane is:

A.$60^{\circ}$
B.$0^{\circ}$
C.$120^{\circ}$
D.$180^{\circ}$
EasySolve

Phenanthrene is an aromatic compound and follows Hückel's $(4n+2)\pi$ electron rule. The value of $n$ is:

A.0
B.1
C.2
D.3
MediumSolve

The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is:

A.The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed conformation has no torsional strain.
B.The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has a torsional strain.
C.The staggered conformation of ethane is more stable than eclipsed conformation because staggered conformation has no torsional strain.
D.The staggered conformation of ethane is less stable than eclipsed conformation because staggered conformation has a torsional strain.
EasySolve

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →