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NEET CHEMISTRYThe d-and f-Block ElementsMedium

Question

Given below are two statements: Statement I: Cr2+Cr^{2+} is oxidising agent and Mn3+Mn^{3+} is a reducing agent in nature. Statement II: Sc3+Sc^{3+} compounds are repelled by the applied magnetic field. In light of the above statements, choose the most appropriate answer from the options given below:

A

Both I and II are correct.

B

Both I and II are incorrect.

C

I is correct but II is incorrect.

D

I is incorrect but II is correct.

Step-by-Step Solution

Statement I is incorrect: Cr2+Cr^{2+} acts as a strong reducing agent because losing an electron oxidises it to Cr3+Cr^{3+}, which has a highly stable half-filled t2g3t_{2g}^3 configuration. On the other hand, Mn3+Mn^{3+} acts as a strong oxidising agent because accepting an electron reduces it to Mn2+Mn^{2+}, which has a highly stable half-filled d5d^5 configuration . Statement II is correct: Scandium in its +3 oxidation state (Sc3+Sc^{3+}) has a 3d03d^0 electronic configuration. Since it has zero unpaired electrons, it is diamagnetic. Diamagnetic substances are repelled by an applied magnetic field .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementsstatementsstatementoxidisingreducingnature

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The $E^\circ$ value for the $Mn^{3+}/Mn^{2+}$ couple is more positive than that of $Cr^{3+}/Cr^{2+}$ or $Fe^{3+}/Fe^{2+}$ due to change of:

A.$d^5$ to $d^2$ configuration
B.$d^4$ to $d^5$ configuration
C.$d^3$ to $d^5$ configuration
D.$d^5$ to $d^4$ configuration
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The catalytic activity of transition metals is due to:

A.High enthalpy of atomization
B.Paramagnetic behaviour
C.Colour of hydrated ions
D.Variable oxidation states
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The manganate and permanganate ions are tetrahedral, due to:

A.The π-bonding involves the overlap of d-orbitals of oxygen with d-orbitals of manganese.
B.The π-bonding involves the overlap of p-orbitals of oxygen with d-orbitals of manganese.
C.Absence of π-bonding.
D.The π-bonding involves the overlap of p-orbitals of oxygen with p-orbitals of manganese.
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The incorrect statement among the following is:

A.Lanthanoids are good conductors of heat and electricity.
B.Actinoids are highly reactive metals, especially when finely divided.
C.Actinoid contraction is greater for element to element than Lanthanoid contraction.
D.Most of the trivalent Lanthanoid ions are colourless in the solid-state.
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When neutral or faintly alkaline $KMnO_4$ is treated with potassium iodide, iodide ion is converted into 'X'. 'X' is:

A.$I_2$
B.$IO_4^-$
C.$IO_3^-$
D.$IO^-$
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Identify the incorrect statement among the following:

A.There is a decrease in the radii of the atoms or ions as one proceeds from $\text{La}$ to $\text{Lu}$.
B.Lanthanoid contraction is the accumulation of successive shrinkages.
C.As a result of lanthanoid contraction, the properties of 4d series of the transition elements have no similarities with the 5d series of elements.
D.Shielding power of 4f electrons is quite weak.
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Acidified $K_2Cr_2O_7$ solution turns green when $Na_2SO_3$ is added to it. This is due to the formation of:

A.$CrO_4^{2-}$
B.$Cr_2(SO_3)_3$
C.$CrSO_4$
D.$Cr_2(SO_4)_3$
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Which of the following ions will exhibit colour in aqueous solutions?

A.$La^{3+} (Z=57)$
B.$Ti^{3+} (Z=22)$
C.$Lu^{3+} (Z=71)$
D.$Sc^{3+} (Z=21)$
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