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NEET CHEMISTRYAldehydes, Ketones and Carboxylic AcidsMedium

Question

The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B), acetic acid (C), and formic acid (D) is:

A

B > A > D > C

B

B > D > C > A

C

A > B > C > D

D

A > C > B > D

Step-by-Step Solution

The acidity of carboxylic acids depends on the stability of the carboxylate anion formed after losing a proton. This stability is influenced by Inductive Effects:

  1. Electron-Withdrawing Groups (EWG): Groups like halogens exert a negative inductive effect (-I), dispersing the negative charge on the anion and increasing stability (and acidity). Fluorine is more electronegative than Chlorine, so the -I effect of CF3-CF_3 is stronger than that of CCl3-CCl_3. Thus, Trifluoroacetic acid (B) > Trichloroacetic acid (A).
  2. Electron-Donating Groups (EDG): Alkyl groups like methyl (CH3-CH_3) exert a positive inductive effect (+I), intensifying the negative charge and destabilizing the anion (decreasing acidity). Formic acid (HCOOHHCOOH) has no alkyl group, while Acetic acid (CH3COOHCH_3COOH) has a methyl group. Thus, Formic acid (D) > Acetic acid (C).

Combining these trends, the order is B > A > D > C.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Aldehydes, Ketones and Carboxylic Acids. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAldehydes, Ketones and Carboxylic Acidscorrectdecreasingstrengthtrichloroacetictrifluoroacetic

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