Question
The correct order of ionic radii of , , , and is: (Atomic nos. Y = 39, La = 57, Eu = 63, Lu = 71)
Due to the lanthanoid contraction, there is a steady decrease in the ionic radii of ions as the atomic number increases from Lanthanum to Lutetium. Therefore, the order among the given lanthanoids is . Yttrium () belongs to the 4d transition series (Period 5) and is placed just above Lanthanum in Group 3. Its ionic radius is significantly smaller than that of and is comparable to the heavier lanthanoids (approx. 90 pm). Although strictly speaking (86 pm) is slightly smaller than , the most appropriate sequence among the given options that correctly places as the largest and maintains the relative order for the lanthanoids is .
This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.
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